Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and PowerLeeds, F. H. (Frank Henley)
Science
Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and Power
Leeds, F. H. (Frank Henley)
Acetylene
SUBSIDIARY PURIFYING MATERIALS.--Among minor reagents suggested as
purifying substances for acetylene may be mentioned potassium
permanganate, barium peroxide, potassium bichromate, sodium plumbate and
arsenious oxide. According to Benz the first two do not remove the
sulphuretted hydrogen completely, and oxidise the acetylene to some
extent; while potassium bichromate leaves some sulphur and phosphorus
behind in the gas. Sodium plumbate has been suggested by Morel, but it is
a question whether its action on the impurities would not be too violent
and whether it would be free from action on the acetylene itself. The use
of arsenious oxide dissolved in a strong acid, and the solution absorbed
in pumice or kieselguhr has been protected by G. F. Jaubert. The
phosphine is said to combine with the arsenic to form an insoluble
brownish compound. In 1902 Javal patented a mixture of 1 part of
potassium permanganate, 5 of "sulphuric acid," and 1 of water absorbed in
4 parts of infusorial earth. The acid constantly neutralised by the
ammonia of the crude gas is as constantly replaced by fresh acid formed
by the oxidation of the sulphuretted hydrogen; and this free acid, acting
upon the permanganate, liberates manganese peroxide, which is claimed to
destroy the phosphorus and sulphur compounds present in the crude
acetylene.
ÉPURÈNE.--A purifying material to which the name of épurène has been
given has been described, by Mauricheau-Beaupré, as consisting of a
mixture of ferric chloride and ferric oxide in the proportion of 2
molecules, or 650 parts, of the former with one molecule, or 160 parts,
of the latter, together with a suitable quantity of infusorial earth. In
the course of preparation, however, 0.1 to 0.2 per cent. of mercuric
chloride is introduced into the material. This mercuric chloride is said
to form an additive compound with the phosphine of the crude acetylene,
which compound is decomposed by the ferric chloride, and the mercuric
chloride recovered. The latter therefore is supposed to act only as a
carrier of the phosphine to the ferric chloride and oxide, by which it is
oxidised according to the equation:
8Fe_2Cl_6 + 4Fe_2O_3 + 3PH_3 = 12Fe_2Cl_4 + 3H_3PO_4.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account