Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and PowerLeeds, F. H. (Frank Henley)
Science
Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and Power
Leeds, F. H. (Frank Henley)
Acetylene
Thus the ultimate products are phosphoric acid and ferrous chloride,
which on exposure to air is oxidised to ferric chloride and oxide. It is
said that this revivification of the fouled or spent épurène takes place
in from 20 to 48 hours when it is spread in the open in thin layers, or
it may be partially or wholly revivified _in situ_ by adding a small
proportion of air to the crude acetylene as it enters the purifier. The
addition of 1 to 2 per cent. of air, according to Mauricheau-Beaupré,
suffices to double the purifying capacity of one charge of the material,
while a larger proportion would achieve its continuous revivification.
Épurène is said to purify 10,000 to 11,000 litres of crude acetylene per
kilogramme, or, say, 160 to 176 cubic feet per pound, when the acetylene
contains on the average 0.05 per cent, by volume of phosphine.
For employment in all acetylene installations smaller than those which
serve complete villages, a solid purifying material is preferable to a
liquid one. This is partly due to the extreme difficulty of subdividing a
stream of gas so that it shall pass through a single mass of liquid in
small enough bubbles for the impurities to be removed by the time the gas
arrives at the surface. This time cannot be prolonged without increasing
the depth of liquid in the vessel, and the greater the depth of liquid,
the more pressure is consumed in forcing the gas through it. Perfect
purification by means of fluid reagents unattended by too great a
consumption of pressure is only to be effected by a mechanical scrubber
such as is used on coal-gas works, wherein, by the agency of external
power, the gas comes in contact with large numbers of solid surfaces kept
constantly wetted; or by the adoption of a tall tower filled with porous
matter or hollow balls over which a continuous or intermittent stream of
the liquid purifying reagent is made to trickle, and neither of these
devices is exactly suited to the requirements of a domestic acetylene
installation. When a solid material having a proper degree of porosity or
aggregation is selected, the stream of gas passing through it is broken
up most thoroughly, and by employing several separate layers of such
material, every portion of the gas is exposed equally to the action of
the chemical reagent by the time the gas emerges from the vessel. The
amount of pressure so consumed is less than that in a liquid purifier
where much fluid is present; but, on the other hand, the loss of pressure
is absolutely constant at all times in a liquid purifier, provided the
head of liquid is maintained at the same point. A badly chosen solid
purifying agent may exhibit excessive pressure absorption as it becomes
partly spent. A solid purifier, moreover, has the advantage that it may
simultaneously act as a drier for the gas; a liquid purifier, in which
the fluid is mainly water, obviously cannot behave in a similar fashion
For thorough purification it is necessary that the gas shall actually
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