Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and PowerLeeds, F. H. (Frank Henley)
Science
Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and Power
Leeds, F. H. (Frank Henley)
Acetylene
capable of being lifted out for cleaning. The lid may be made tight
either by a clamp and rubber or leather washer, or by a liquid seal. If
the purifying material is not hygroscopic, water, calcium chloride
solution, or dilute glycerin may be used for sealing purposes; but if the
material, or any part of it, does absorb water, the liquid in the seal
should be some non-aqueous fluid like lubricating oil. Clamped lids are
more suitable for small purifiers, sealed lids for large vessels. Care
must be taken that condensation products cannot collect in the purifying
vessel. If a separate drying material is employed in the same purifier
the space it takes must be considered separately from that needed by the
active chemical reagent. When emptying a foul purifier it should be
recollected that the material may be corrosive, and being saturated with
acetylene is likely to catch fire in presence of a light.
Purifiers charged with heratol are stated, however, to admit of a more
rapid flow of the gas through them than that stated above for puratylene.
The ordinary allowance is 1 lb. of heratol for every cubic foot per hour
of acetylene passing, with a minimum charge of 7 lb. of the material. As
the quantity of material in the purifier is increased, however, the flow
of gas per hour may be proportionately increased, _e.g._, a purifier
charged with 132 lb. of heratol should purify 144 cubic feet of acetylene
per hour.
In the systematic purification of acetylene, the practical question
arises as to how the attendant is to tell when his purifiers approach
exhaustion and need recharging; for if it is undesirable to pass crude
gas into the service, it is equally undesirable to waste so comparatively
expensive a material as a purifying reagent. In Chapter XIV. it will be
shown that there are chemical methods of testing for the presence, or
determining the proportion, of phosphorus and sulphur in acetylene; but
these are not suitable for employment by the ordinary gas-maker. Heil has
stated that the purity of the gas may be judged by an inspection of its
atmospheric flame as given by a Bunsen burner. Pure acetylene gives a
perfectly transparent moderately dark blue flame, which has an inner cone
of a pale yellowish green colour; while the impure gas yields a longer
flame of an opaque orange-red tint with a bluish red inner zone. It
should be noted, however, that particles of lime dust in the gas may
cause the atmospheric flame to be reddish or yellowish (by presence of
calcium or sodium) quite apart from ordinary impurities; and for various
other reasons this appearance of the non-luminous flame is scarcely to be
relied upon. The simplest means of ascertaining definitely whether a
purifier is sufficiently active consists in the use of the test-papers
prepared by E. Merck of Darmstadt according to G. Keppeler's
prescription. These papers, cut to a convenient size, are put up in small
books from which they may be torn one at a time. In order to test whether
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