Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and PowerLeeds, F. H. (Frank Henley)
Science
Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and Power
Leeds, F. H. (Frank Henley)
Acetylene
gas is sufficiently purified, one of the papers is moistened with
hydrochloric acid of 10 per cent. strength, and the gas issuing from a
pet-cock or burner orifice is allowed to impinge on the moistened part.
The original black or dark grey colour of the paper is changed to white
if the gas contains a notable amount of impurity, but remains unchanged
if the gas is adequately purified. The paper consists of a specially
prepared black porous paper which has been dipped in a solution of
mercuric chloride (corrosive sublimate) and dried. Moistening the paper
with hydrochloric acid provides in a convenient form for application
Bergé's solution for the detection of phosphine (_vide_ Chapter
XIV.). The Keppeler test-papers turn white when the gas contains either
ammonia, phosphine, siliciuretted hydrogen, sulphuretted hydrogen or
organic sulphur compounds, but with carbon disulphide the change is slow.
Thus the paper serves as a test for all the impurities likely to occur in
acetylene. The sensitiveness of the test is such that gas containing
about 0.15 milligramme of sulphur, and the same amount of phosphorus, per
litre (= 0.0655 grain per cubic foot) imparts in five minutes a distinct
white mark to the moistened part of the paper, while gas containing 0.05
milligramme of sulphur per litre (= 0.022 grain per cubic foot) gives in
two minutes a dull white mark visible only by careful inspection. If,
therefore, a distinct white mark appears on moistened Keppeler paper when
it is exposed for five minutes to a jet of acetylene, the latter is
inadequately purified. If the gas has passed through a purifier, this
test indicates that the material is not efficient, and that the purifier
needs recharging. The moistening of the Keppeler paper with hydrochloric
acid before use is essential, because if not acidified the paper is
marked by acetylene itself. The books of Keppeler papers are put up in a
case which also contains a bottle of acid for moistening them as required
and are obtainable wholesale of E. Merek, 16 Jewry Street, London, E.C.,
and retail of the usual dealers in chemicals. If Keppeler's test-papers
are not available, the purifier should be recharged as a matter of
routine as soon as a given quantity of carbide--proportioned to the
purifying capacity of the charge of purifying material--has been used
since the last recharging. Thus the purifier may conveniently contain
enough material to purify the gas evolved from two drums of carbide, in
which case it would need recharging when every second drum of carbide is
opened.
REGULATIONS AS TO PURIFICATION.--The British Acetylene
Association has issued the following set of regulations as to purifying
material and purifiers for acetylene:
Efficient purifying material and purifiers shall comply with the
following requirements:
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