Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and PowerLeeds, F. H. (Frank Henley)
Science
Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and Power
Leeds, F. H. (Frank Henley)
Acetylene
PHYSICAL PROPERTIES.--Acetylene is a gas at ordinary temperatures,
colourless, and, when pure, having a not unpleasant, so-called "ethereal"
odour. Its density, or specific gravity, referred to air as unity, has
been found experimentally by Leduc to be 0.9056. It is customary to adopt
the value 0.91 for calculations into which the density of the gas enters
(_vide_ Chapter VII.). The density of a gas is important not only
for the determination of the size of mains needed to convey it at a given
rate of flow under a given pressure, as explained in Chapter VII., but
also because the volume of gas which will pass through small orifices in
a given time depends on its density. According to Graham's well-known law
of the effusion of gases, the velocity with which a gas effuses varies
directly as the square root of the difference of pressure on the two
sides of the opening, and inversely as the square root of the density of
the gas. Hence it follows that the volume of gas which escapes through a
porous pipe, an imperfect joint, or a burner orifice is, provided the
pressure in the gas-pipe is the same, a function of the square root of
the density of the gas. Hence this density has to be taken into
consideration in the construction of burners, i.e., a burner required to
pass a gas of high density must have a larger orifice than one for a gas
of low density, if the rate of flow of gas is to be the same under the
same pressure. This, however, is a question for the burner manufacturers,
who already make special burners for gases of different densities, and it
need not trouble the consumer of acetylene, who should always use burners
devised for the consumption of that gas. But the Law of effusion
indicates that the volume of acetylene which can escape from a leaky
supply-pipe will be less than the volume of a gas of lower density,
_e.g._, coal-gas, if the pressure in the pipe is the same for both.
This implies that on an extensive distributing system, in which for
practical reasons leakage is not wholly avoidable, the loss of gas
through leakage will be less for acetylene than for coal-gas, given the
same distributing pressure. If _v_ = the loss of acetylene from a
distributing system and _v'_ = the loss of coal-gas from a similar
system worked at the same pressure, both losses being expressed in
volumes (cubic feet) per hour, and the coal-gas being assumed to have a
density of 0.04, then
(1) (_v_/_v'_) = (0.40 / 0.91)^(1/2) = 0.663
or, _v_ = 0.663_v'_,
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