Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and PowerLeeds, F. H. (Frank Henley)
Science
Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and Power
Leeds, F. H. (Frank Henley)
Acetylene
which signifies that the loss of acetylene by leakage under the same
conditions of pressure, &c., will be only 0.663 times that of the loss of
coal-gas. In practice, however, the pressures at which the gases are
usually sent through mains are not identical, being greater in the case
of acetylene than in that of coal-gas. Formula (1) therefore requires
correction whenever the pressures are different, and calling the pressure
at which the acetylene exists in the main _p_, and the corresponding
pressure of the coal-gas _p'_, the relative losses by leakage are--
(2) (_v_/_v'_) = (0.40 / 0.91)^(1/2) x (_p_/_p'_)^(1/2)
_v_ = 0.663_v'_ x (_p_/_p'_)^(1/2)
It will be evident that whenever the value of the fraction
(_p_/_p'_)^(1/2), is less than 1.5, _i.e._, whenever the pressure of
the acetylene does not exceed double that of the coal-gas present in
pipes of given porosity or unsoundness, the loss of acetylene will be
less than that of coal-gas. This is important, especially in the case of
large village acetylene installations, where after a time it would be
impossible to avoid some imperfect joints, fractured pipes, &c.,
throughout the extensive distributing mains. The same loss of gas by
leakage would represent a far higher pecuniary value with acetylene than
with coal-gas, because the former must always be more costly per unit of
volume than the latter. Hence it is important to recognise that the rate
of leakage, _cteris paribus_, is less with acetylene, and it is
also important to observe the economical advantage, at least in terms of
gas or calcium carbide, of sending the acetylene into the mains at as low
a pressure as is compatible with the length of those mains and the
character of the consumers' burners. As follows from what will be said in
Chapter VII., a high initial pressure makes for economy in the prime cost
of, and in the expense of laying, the mains, by enabling the diameter of
those mains to be diminished; but the purchase and erection of the
distributing system are capital expenses, while a constant expenditure
upon carbide to meet loss by leakage falls upon revenue.
The critical temperature of acetylene, _i.e._, the temperature below
which an abrupt change from the gaseous to the liquid state takes place
if the pressure is sufficiently high, is 37° C., and the critical
pressure, _i.e._, the pressure under which that change takes place
at that temperature, is nearly 68 atmospheres. Below the critical
temperature, a lower pressure than this effects liquefaction of the gas,
_i.e._, at 13.5° C. a pressure of 32.77 atmospheres, at 0° C., 21.53
atmospheres (Ansdell, _cf._ Chapter XI.). These data are of
comparatively little practical importance, owing to the fact that, as
explained in Chapter XI., liquefied acetylene cannot be safely utilised.
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