Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and PowerLeeds, F. H. (Frank Henley)
Science
Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and Power
Leeds, F. H. (Frank Henley)
Acetylene
The specific heat of acetylene is given by M. A. Morel at 0.310, though
he has not stated by whom the value was determined. For the purpose of a
calculation in Chapter III. the specific heat at constant pressure was
assumed to be 0.25, which, in the absence of precise information, appears
somewhat more probable as an approximation to the truth. The ratio
(_k_ or C_p/C_v ) of the specific heat at constant pressure to that
at constant volume has been found by Maneuvrier and Fournier to be 1.26;
but they did not measure the specific heat itself. [Footnote: The ratio
1.26 _k_ or (C_p/C_v) has been given in many text-books as the value
of the specific heat of acetylene, whereas this value should obviously be
only about one-fourth or one-fifth of 1.26.
By employing the ordinary gas laws it is possible approximately to
calculate the specific heat of acetylene from Maneuvrier and Fournier's
ratio. Taking the molecular weight of acetylene as 26, we have
26 C_p - 26 C_v = 2 cal.,
and
C_p = 1.26 C_v.
From this it follows that C_p, _i.e._, the specific heat at constant
pressure of acetylene, should be 0.373.] It will be seen that this value
for _k_ differs considerably from the corresponding ratio in the
case of air and many common gases, where it is usually 1.41; the figure
approaches more closely that given for nitrous oxide. For the specific
heat of calcium carbide Carlson quotes the following figures:
0° 1000° 1500° 2000° 2500° 3000° 3500°
0.247 0.271 0.296 0.325 0.344 0.363 0.381
The molecular volume of acetylene is 0.8132 (oxygen = 1).
According to the international atomic weights adopted in 1908, the
molecular weight of acetylene is 26.016 if O = 16; in round numbers, as
ordinarily used, it is 26. Employing the latest data for the weight of 1
litre of dry hydrogen and of dry normal air containing 0.04 per cent. of
carbon dioxide at a temperature of 0° C. and a barometric pressure of 760
mm. in the latitude of London, viz., 0.089916 and 1.29395 grammes
respectively (Castell-Evans), it now becomes possible to give the weight
of a known volume of dry or moist acetylene as measured under stated
conditions with some degree of accuracy. Using 26.016 as the molecular
weight of the gas (O = 16), 1 litre of dry acetylene at 0° C. and 760 mm.
weighs 1.16963 grammes, or 1 gramme measures 0.854973 litre. From this it
follows that the theoretical specific gravity of the gas at 0°/0° C. is
0.9039 (air = 1), a figure which may be compared with Leduc's
experimental value of 0.9056. Taking as the coefficient of expansion at
constant pressure the figure already given, viz., 0.003738, the weights
and measures of dry and moist acetylene observed under British conditions
(60° F. and 30 inches of mercury) become approximately:
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