Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and PowerLeeds, F. H. (Frank Henley)
Science
Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and Power
Leeds, F. H. (Frank Henley)
Acetylene
The mean coefficient of expansion of gaseous acetylene between 0° C. and
100° C., is, under constant pressure, 0.003738; under constant volume,
0.003724. This means that, if the pressure is constant, 0.003738
represents the increase in volume of a given mass of gaseous acetylene
when its temperature is raised one degree (C.), divided by the volume of
the same mass at 0° C. The coefficients of expansion of air are: under
constant pressure, 0.003671; under constant volume, 0.003665; and those
of the simple gases (nitrogen, hydrogen, oxygen) are very nearly the
same. Strictly speaking the table given in Chapter XIV., for facilitating
the correction of the volume of gas measured over water, is not quite
correct for acetylene, owing to the difference in the coefficients of
expansion of acetylene and the simple gases for which the table was drawn
up, but practically no appreciable error can ensue from its use. It is,
however, for the correction of volumes of gases measured at different
temperatures to one (normal) temperature, and, broadly, for determining
the change of volume which a given mass of the gas will undergo with
change of temperature, that the coefficient of expansion of a gas becomes
an important factor industrially.
Ansdell has found the density of liquid acetylene to range from 0.460 at
-7° C. to 0.364 at +35.8° C., being 0.451 at 0° C. Taking the volume of
the liquid at -7° as unity, it becomes 1.264 at 35.8°, and thence Ansdell
infers that the mean coefficient of expansion per degree is 0.00489° for
the total range of pressure." Assuming that the liquid was under the same
pressure at the two temperatures, the coefficient of expansion per degree
Centigrade would be 0.00605, which agrees more nearly with the figure
0.007 which is quoted, by Fouché As mentioned before, data referring to
liquid (_i.e._, liquefied) acetylene are of no practical importance,
because the substance is too dangerous to use. They are, however,
interesting in so far as they indicate the differences in properties
between acetylene converted into the liquid state by great pressure, and
acetylene dissolved in acetone under less pressure; which differences
make the solution fit for employment. It may be observed that as the
solution of acetylene in acetone is a liquid, the acetylene must exist
therein as a liquid; it is, in fact, liquid acetylene in a state of
dilution, the diluent being an exothermic and comparatively stable body.
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