Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and PowerLeeds, F. H. (Frank Henley)
Science
Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and Power
Leeds, F. H. (Frank Henley)
Acetylene
Catani has published the following determinations of the temperature
yielded by acetylene when burnt with cold and hot air and also with
oxygen:
Acetylene and cold air . . . . . . 2568° C.
" air at 500° C . . . . 2780° C.
" air at 1000° C . . . . 3000° C.
" oxygen . . . . . . 4160° C.
EXPLOSIVE LIMITS.--The range of explosibility of mixtures of acetylene
and air has been determined by various observers. Eitner's figures for
the lower and upper explosive limits, when the mixture, at 62.6° F., is
in a tube 19 mm. in diameter, and contains 1.9 per cent. of aqueous
vapour, are 3.35 and 52.3 per cent. of acetylene (_cf._ Chapter X.).
In this case the mixture was fired by electric spark. In wider vessels,
the upper explosive limit, when the mixture was fired by a Bunsen flame,
was found to be as high as 75 per cent. of acetylene. Eitner also found
that when 13 of the 21 volumes of oxygen in air are displaced by carbon
dioxide, a mixture of such "carbon dioxide air" with acetylene is
inexplosive in all proportions. Also that when carbon dioxide is added to
a mixture of acetylene and air, an explosion no longer occurs when the
carbon dioxide amounts to 46 volumes or more to every 54 volumes of air,
whatever may be the proportion of acetylene in the mixture. [Footnote:
According to Caro, if acetylene is added to a mixture composed of 55 per
cent. by volume of air and 45 per cent. of carbon dioxide, the whole is
only explosive when the proportion of acetylene lies between 5.0 and 5.8
per cent. Caro has also quoted the effect of various inflammable vapours
upon the explosive limits of acetylene, his results being referred to in
Chapter X.] These figures are valuable in connexion with the prevention
of the formation of explosive mixtures of air and acetylene when new
mains or plant are being brought into operation (_cf._ Chapter
VII.). Eitner has also shown, by direct investigation on mixtures of
other combustible gases and air, that the range of explosibility is
greatly reduced by increase in the proportion of aqueous vapour present.
As the proportion of aqueous vapour in gas standing over water increases
with the temperature the range of explosibility of mixtures of a
combustible gas and air is naturally and automatically reduced when the
temperature rises, provided the mixture is in contact with water. Thus at
17.0° C., mixtures of hydrogen, air, and aqueous vapour containing from
9.3 to 65.0 per cent, of hydrogen are explosive, whereas at 78.1° C.,
provided the mixture is saturated with aqueous vapour, explosion occurs
only when the percentage of hydrogen in the mixture is between 11.2 and
21.9. The range of explosibility of mixtures of acetylene and air is
similarly reduced by the addition of aqueous vapour (though the exact
figures have not been experimentally ascertained); and hence it follows
that when the temperature in an acetylene generator in which water is in
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