Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and PowerLeeds, F. H. (Frank Henley)
Science
Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and Power
Leeds, F. H. (Frank Henley)
Acetylene
excess, or in a gasholder, rises, the risk of explosion, if air is mixed
with the gas, is automatically reduced with the rise in temperature by
reason of the higher proportion of aqueous vapour which the gas will
retain at the higher temperature. This fact is alluded to in Chapter II.
Acetone vapour also acts similarly in lowering the upper explosive limit
of acetylene (_cf._ Chapter XI.).
It may perhaps be well to indicate briefly the practical significance of
the range of explosibility of a mixture of air and a combustible gas,
such as acetylene. The lower explosive limit is the lowest percentage of
combustible gas in the mixture of it and air at which explosion will
occur in the mixture if a light or spark is applied to it. If the
combustible gas is present in the mixture with air in less than that
percentage explosion is impossible. The upper explosive limit is the
highest percentage of combustible gas in the mixture of it and air at
which explosion will occur in the mixture if a light or spark is applied
to it. If the combustible gas is present in the mixture with air in more
than that percentage explosion is impossible. Mixtures, however, in which
the percentage of combustible gas lies between these two limits will
explode when a light or spark is applied to them; and the comprehensive
term "range of explosibility" is used to cover all lying between the two
explosive limits. If, then, a naked light is applied to a vessel
containing a mixture of a combustible gas and air, in which mixture the
proportion of combustible gas is below the lower limit of explosibility,
the gas will not take fire, but the light will continue to burn, deriving
its necessary oxygen from the excess of air present. On the other hand,
if a light is applied to a vessel containing a mixture of a combustible
gas and air, in which mixture the proportion of combustible gas is above
the upper limit of explosibility, the light will be extinguished, and
within the vessel the gaseous mixture will not burn; but it may burn at
the open mouth of the vessel as it comes in contact with the surrounding
air, until by diffusion, &c., sufficient air has entered the vessel to
form, with the remaining gas, a mixture lying within the explosive
limits, when an explosion will occur. Again, if a gaseous mixture
containing less of its combustible constituent than is necessary to
attain the lower explosive limit escapes from an open-ended pipe and a
light is applied to it, the mixture will not burn as a useful compact
flame (if, indeed, it fires at all); if the mixture contains more of its
combustible constituent than is required to attain the upper explosive
limit, that mixture will burn quietly at the mouth of the pipe and will
be free from any tendency to fire back into the pipe--assuming, of
course, that the gaseous mixture within the pipe is constantly travelling
towards the open end. If, however, a gaseous mixture containing a
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