Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and Power — John Shaqi
Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and PowerLeeds, F. H. (Frank Henley)
Science
Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and Power
Leeds, F. H. (Frank Henley)
Acetylene
reasonable margin of safety the mixing apparatus must be so devised that
the proportion of hydrocarbon vapour in the air-gas can never exceed 2
per cent. From Chapter VI. it will be evident that a little more than 2
per cent. of benzene, pentane or benzoline vapour in air forms an
explosive mixture. What is the lowest proportion of such vapours in
admixture with air which will serve on combustion to maintain a mantle in
a state of incandescence, or even to afford a flame at all, does not
appear to have been precisely determined, but it cannot be much below 1-
1/2 per cent. Hence the apparatus for producing air-gas of this first
class must be provided with controlling or governing devices of such
nicety that the proportion of hydrocarbon vapour in the air-gas is
maintained between about 1-1/2 and 2 per cent. It is fair to say that in
normal working conditions a number of devices appear to fulfil this
requirement satisfactorily. The second of the two mixtures referred to
above, viz., air with more hydrocarbon vapour than constitutes an
explosive mixture, is primarily suitable for combustion in self-luminous
burners, but may also be consumed in properly designed incandescent
burners. But the generating apparatus for such air-gas must be equipped
with some governing or controlling device which will ensure the
proportion of hydrocarbon vapour in the mixture never falling below, say,
7 per cent. On the other hand, if saturation of the air with the vapour
is practically attained, should the temperature of the gas fall before it
arrives at the point of combustion, part of the spirit will condense out,
and the product will thus lose part of its illuminating or calorific
intensity, besides partially filling the pipes with liquid products of
condensation. The loss of intensity in the gas during cold weather may or
may not be inconvenient according to circumstances; but the removal of
part of the combustible material brings the residual air-gas nearer to
its limit of explosibility--for it is simply a mixture of combustible
vapour with air, which, normally, is not explosive because the proportion
of spirit is too high--and thus, when led into an atmospheric burner, the
extra amount of air introduced at the injector jets may cause the mixture
to be an explosive mixture of air and spirit, so that it will take fire
within the burner tube instead of burning quietly at the proper orifice.
This matter will be made clearer on studying what is said about explosive
limits in Chapter VI., and what is stated about incandescent acetylene
(carburetted or not) in Chapters IX. and X. Clearly, however, high-grade
air-gas is only suitable for preparation at the immediate spot where it
is to be consumed; it cannot be supplied to a complete district unless it
is intentionally made of such lower intensity that the proportion of
spirit is too small ever to allow of partial deposition in the mains
during the winter.
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