Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and PowerLeeds, F. H. (Frank Henley)
Science
Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and Power
Leeds, F. H. (Frank Henley)
Acetylene
NATURE OF LUMINOUS FLAMES.--When referring to methods of obtaining
artificial light by means of processes involving combustion or oxidation,
the term "incandescence" is usually limited to those forms of burner in
which some extraneous substance, such as a "mantle," is raised to a
brilliant white heat. Though convenient, the phrase is a mere convention,
for all artificial illuminants, even including the electric light, which
exhibit a useful degree of intensity depend on the same principle of
incandescence. Adopting the convention, however, an incandescent burner
is one in which the fuel burns with a non-luminous or atmospheric flame,
the light being produced by causing that flame to play upon some
extraneous refractory body having the property of emitting much light
when it is raised to a sufficiently high temperature; while a luminous
burner is one in which the fuel is allowed to combine with atmospheric
oxygen in such a way that one or more of the constituents in the gas
evolves light as it suffers combustion. From the strictly chemical point
of view the light-giving substance in the incandescent flame lasts
indefinitely, for it experiences no change except in temperature; whereas
the light-giving substance in a luminous flame lasts but for an instant,
for it only evolves light during the act of its combination with the
oxygen of the atmosphere. Any fluid combustible which burns with a flame
can be made to give light on the incandescent system, for all such
materials either burn naturally, or can be made to burn with a non-
luminous flame, which can be employed to raise the temperature of some
mantle; but only those fuels can be burnt on the self-luminous system
which contain some ingredient that is liberated in the elemental state in
the flame, the said ingredient being one which combines energetically
with oxygen so as to liberate much local heat. In practice, just as there
are only two or three substances which are suitable for the construction
of an incandescent mantle, so there is only one which renders a flame
usefully self-luminous, viz., carbon; and therefore only such fuels as
contain carbon among their constituents can be burnt so as to produce
light without the assistance of the mantle. But inasmuch as it is
necessary for the evolution of light by the combustion of carbon that
that carbon shall be in the free state, only those carbonaceous fuels
yield light without the mantle in which the carbonaceous ingredient is
dissociated into its elements before it is consumed. For instance,
alcohol and carbon monoxide are both combustible, and both contain
carbon; but they yield non-luminous flames, for the carbon burns to
carbon dioxide in ordinary conditions without assuming the solid form;
ether, petroleum, acetylene, and some of the hydrocarbons of coal-gas do
emit light on combustion, for part of their carbon is so liberated. The
quantity of light emitted by the glowing substance increases as the
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