Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and PowerLeeds, F. H. (Frank Henley)
Science
Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and Power
Leeds, F. H. (Frank Henley)
Acetylene
temperature of that substance rises: the gain in light being equal to the
fifth or higher power of the gain in heat; [Footnote: Calculated from
absolute zero.] therefore unnecessary dissipation of heat from a flame is
one of the most important matters to be guarded against if that flame is
to be an economical illuminant. But the amount of heat liberated when a
certain weight (or volume) of a particular fuel combines with a
sufficient quantity of oxygen to oxidise it wholly is absolutely fixed,
and is exactly the same whether that fuel is made to give a luminous or a
non-luminous flame. Nevertheless the atmospheric flame given by a certain
fuel may be appreciably hotter than its luminous flame, because the
former is usually smaller than the latter. Unless the luminous flame of a
rich fuel is made to expose a wide surface to the air, part of its carbon
may escape ultimate combustion; soot or smoke may be produced, and some
of the most valuable heat-giving substance will be wasted. But if the
flame is made to expose a large surface to the air, it becomes flat or
hollow in shape instead of being cylindrical and solid, and therefore in
proportion to its cubical capacity it presents to the cold air a larger
superficies, from which loss of heat by radiation, &c., occurs. Being
larger, too, the heat produced is less concentrated.
It does not fall within the province of the present book to discuss the
relative merits of luminous and incandescent lighting; but it may be
remarked that acetylene ranks with petroleum against coal-gas,
carburetted or non-carburetted water-gas, and semi-water-gas, in showing
a comparatively small degree of increased efficiency when burnt under the
mantle. Any gas which is essentially composed of carbon monoxide or
hydrogen alone (or both together) burns with a non-luminous flame, and
can therefore only be used for illuminating purposes on the incandescent
system; but, broadly speaking, the higher is the latent illuminating
power of the gas itself when burnt in a non-atmospheric burner, the less
marked is the superiority, both from the economical and the hygienic
aspect, of its incandescent flame. It must be remembered also that only a
gas yields a flame when it is burnt; the flame of a paraffin lamp and of
a candle is due to the combustion of the vaporised fuel. Methods of
burning acetylene under the mantle are discussed in Chapter IX.; here
only self-luminous flames are being considered, but the theoretical
question of heat economy applies to both processes.
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