Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and PowerLeeds, F. H. (Frank Henley)
Science
Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and Power
Leeds, F. H. (Frank Henley)
Acetylene
It has been stated that in order to avoid loss of heat from a flame
through the burner, that burner should present only a small mass of
material (_i.e._, be as light in weight as possible), and should be
constructed of a bad heat-conductor. But if a small mass of a material
very deficient in heat-conducting properties comes in contact with a
flame, its temperature rises seriously and may approach that of the base
of the flame itself. In the case of coal-gas this phenomenon is not
objectionable, is even advantageous, and it explains why a burner made of
steatite, which conducts heat badly, in always more economical (of heat
and therefore of light) than an iron one. In the case of acetylene the
same rule should, and undoubtedly does, apply also; but it is
complicated, and its effect sometimes neutralised, by a peculiarity of
the gas itself. It has been shown in Chapters II. and VI. that acetylene
polymerises under the influence of heat, being converted into other
bodies of lower illuminating power, together with some elemental carbon.
If, now, acetylene is fed into a burner which, being composed of some
material like steatite possessed of low heat-conducting and radiating
powers, is very hot, and if the burner comprises a tube of sensible
length, the gas that actually arrives at the orifice may no longer be
pure acetylene, but acetylene diluted with inferior illuminating agents,
and accompanied by a certain proportion of carbon. Neglecting the effect
of this carbon, which will be considered in the following paragraph, it
is manifest that the acetylene issuing from a hot burner--assuming its
temperature to exceed the minimum capable of determining polymerisation--
may emit less light per unit of volume than the acetylene escaping from a
cold burner. Proof of this statement is to be found in some experiments
described by Bullier, who observed that when a small "Manchester" or
fish-tail burner was allowed to become naturally hot, the quantity of gas
needed to give the light of one candle (uncorrected) was 1.32 litres, but
when the burner was kept cool by providing it with a jacket in which
water was constantly circulating, only 1.13 litres of acetylene were
necessary to obtain the same illuminating value, this being an economy of
16 per cent.
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