Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and PowerLeeds, F. H. (Frank Henley)
Science
Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and Power
Leeds, F. H. (Frank Henley)
Acetylene
EARLY BURNERS.--One of the chief difficulties encountered in the early
days of the acetylene industry was the design of a satisfactory burner
which should possess a life of reasonable length. The first burners tried
were ordinary oil-gas jets, which resemble the fish-tails used with coal-
gas, but made smaller in every part to allow for the higher illuminating
power of the oil-gas or acetylene per unit of volume. Although the flames
they gave were very brilliant, and indeed have never been surpassed, the
light quickly fell off in intensity owing to the distortion of their
orifices caused by the deposition of solid matter at the edges. Various
explanations have been offered to account for the precipitation of solid
matter at the jets. If the acetylene passes directly to the burner from a
generator having carbide in excess without being washed or filtered in
any way, the gas may carry with it particles of lime dust, which will
collect in the pipes mainly at the points where they are constricted; and
as the pipes will be of comparatively large bore until the actual burner
is readied, it will be chiefly at the orifices where the deposition
occurs. This cause, though trivial, is often overlooked. It will be
obviated whenever the plant is intelligently designed. As the phosphoric
anhydride, or pentoxide, which is produced when a gas containing
phosphorus burns, is a solid body, it may be deposited at the burner
jets. This cause may be removed, or at least minimised, by proper
purification of the acetylene, which means the removal of phosphorus
compounds. Should the gas contain hydrogen silicide siliciuretted
hydrogen), solid silica will be produced similarly, and will play its
part in causing obstruction. According to Lewes the main factor in the
blocking of the burners is the presence of liquid polymerised products in
the acetylene, benzene in particular; for he considers that these bodies
will be absorbed by the porous steatite, and will be decomposed under the
influence of heat in that substance, saturating the steatite with carbon
which, by a "catalytic" action presumably, assists in the deposition of
further quantities of carbon in the burner tube until distortion of the
flame results. Some action of this character possibly occurs; but were it
the sole cause of blockage, the trouble would disappear entirely if the
gas were washed with some suitable heavy oil before entering the burners,
or if the latter were constructed of a non-porous material. It is
certainly true that the purer is the acetylene burnt, both as regards
freedom from phosphorus and absence of products of polymerisation, the
longer do the burners last; and it has been claimed that a burner
constructed at its jets of some non-porous substance, e.g., "ruby," does
not choke as quickly as do steatite ones. Nevertheless, stoppages at the
burners cannot be wholly avoided by these refinements. Gaud has shown
that when pure acetylene is burnt at the normal rate in 1-foot Bray jets,
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account