Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and PowerLeeds, F. H. (Frank Henley)
Science
Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and Power
Leeds, F. H. (Frank Henley)
Acetylene
It is desirable, however, now to discuss one point connected with solid
carbide about which some misconception prevails. Calcium carbide is a
body which evolves an inflammable, or on occasion an explosive, gas when
treated with water; and therefore its presence in a building has been
said to cause a sensible increase in the fire risk because attempts to
extinguish a fire in the ordinary manner with water may cause evolution
of acetylene which should determine a further production of flame and
heat. In the absence of water, calcium carbide is absolutely inert as
regards fire; and on several occasions drums of it have been recovered
uninjured from the basement of a house which has been totally destroyed
by fire. With the exception of small 1-lb. tins of carbide, used only by
cyclists, &c., the material is always put into drums of stout sheet-iron
with riveted or folded seams. Provided the original lid has not been
removed, the drums are air- and water-tight, so that the fireman's hose
may be directed upon them with impunity. When a drum has once been
opened, and not all of its contents have been put into the generator,
ordinary caution--not merely as regards fire, but as regards the
deterioration of carbide when exposed to the atmosphere--suggests either
that the lid must be made air-tight again (not by soldering it),
[Footnote: Carbide drums are not uncommonly fitted with self-sealing or
lever-top lids, which are readily replaced hermetically tight after
opening and partial removal of the contents of the drum.] or preferably
that the rest of the carbide shall be transferred to some convenient
receptacle which can be perfectly closed. [Footnote: It would be a
refinement of caution, though hardly necessary in practice, to fit such a
receptacle with a safety-valve. If then the vessel were subjected to
sudden or severe heating, the expansion of the air and acetylene in it
could not possibly exert a disruptive effect upon the walls of the
receptacle, which, in the absence of the safety-valve, is imaginable.]
Now, assuming this done, the drums are not dependent upon soft solder to
keep them sound, and so they cannot open with heat. Fire and water,
accordingly, cannot affect them, and only two risks remain: if stored in
the basement of a tall building, falling girders, beams or brickwork may
burst them; or if stored on an upper floor, they may fall into the
basement and be burst with the shock--in either event water then having
free access to the contents. But drums of carbide would never be stored
in such positions: a single one would be kept in the generator-house;
several would be stored in a separate room therein, or in some similar
isolated shed. The generator-house or shed would be of one story only;
the drums could neither fall nor have heavy weights fall on them during a
fire; and therefore there is no reason why, if a fire should occur, the
firemen should not be permitted to use their hose in the ordinary
fashion.
Public-domain text, read in full here on John Shaqi.
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