Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and Power — John Shaqi
Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and PowerLeeds, F. H. (Frank Henley)
Science
Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and Power
Leeds, F. H. (Frank Henley)
Acetylene
From the practical aspect what has been said amounts to this: During the
operation of an acetylene generator a large amount of heat is produced,
the quantity of which is beyond human control. It is desirable, for
various reasons, that the temperature shall be kept as low as possible.
There are three substances present to which the heat may be compelled to
transfer itself until it has opportunity to pass into the surrounding
atmosphere: the material of which the apparatus is constructed, the gas
which is in process of evolution, and whichever of the two bodies--
calcium carbide or water--is in excess in the generator. Of these, the
specific heat at constant pressure of acetylene has unfortunately not yet
been determined, but its relative capacity for absorbing heat is
undoubtedly small; moreover the gas could not be permitted to become
sufficiently hot to carry off the heat without grave disadvantages. The
specific heat of calcium carbide is also comparatively small, and there
are similar disadvantages in allowing it to become hot; moreover it is
deficient in heat-conducting power, so that heat communicated to one
portion of the mass does not extend rapidly throughout, but remains
concentrated in one spot, causing the temperature to rise objectionably.
Steel has a sufficient amount of heat-conducting power to prevent undue
concentration in one place; but, as has been stated, its specific heat is
only one-ninth that of water. Water is clearly, therefore, the proper
substance to employ for the dissipation of the heat generated, although
it is strictly speaking almost devoid of heat-conducting power; for not
only is the specific heat of water much greater than that of any other
material present, but it possesses in a high degree the faculty of
absorbing heat throughout its mass, by virtue of the action known as
convection, provided that heat is communicated to it at or near the
bottom, and not too near its upper surface. Moreover, water is a much
more valuable substance for dissipating heat than appears from the
foregoing explanation; for reference to the experiment with the gas-
burner will show that six and a quarter times as much heat can be
absorbed by a given weight of water if it is permitted to change into
steam, as if it is merely raised to the boiling-point; and since by no
urging of the gas-burner can the temperature be raised above 100° C. as
long as any liquid water remains unevaporated, if an excess of water is
employed in an acetylene generator, the temperature inside can never--
except quite locally--exceed 100° C., however fast the carbide be
decomposed. An indefinitely large consumption of water by evaporation in
a generator matters nothing, for the liquid may be considered of no
pecuniary value, and it can all be recovered by condensation in a
subsequent portion of the plant.
Public-domain text, read in full here on John Shaqi.
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