Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and Power — John Shaqi
Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and PowerLeeds, F. H. (Frank Henley)
Science
Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and Power
Leeds, F. H. (Frank Henley)
Acetylene
THE PROCESS OF GENERATION.--Taking 28 as the number of large calories
developed when 64 grammes of ordinary commercial calcium carbide are
decomposed with sufficient water to leave dry solid calcium hydroxide as
the by-product in acetylene generation, this quantity of heat is capable
of exerting any of the following effects. It is sufficient (1) to raise
1000 grammes of water through 28° C., say from 10° C. (50° F., which is
roughly the temperature of ordinary cold water) to 38° C. It is
sufficient (2) to raise 64 grammes of water (a weight equal to that of
the carbide decomposed) through 438° C., if that were possible. It would
raise (3) 311 grammes of water through 90° C., _i.e._, from 10° C.
to the boiling-point. If, however, instead of remaining in the liquid
state, the water were converted into vapour, the same quantity of heat
would suffice (4) to change 44.7 grammes of water at 10° C. into steam at
100° C.; or (5) to change 46.7 grammes of water at 10° C. into vapour at
the same temperature. It is an action of the last character which takes
place in acetylene generators of the most modern and usual pattern, some
of the surplus water being evaporated and carried away as vapour at a
comparatively low temperature with the escaping gas; for it must be
remembered that although steam, as such, condenses into liquid water
immediately the surrounding temperature falls below 100° C., the vapour
of water remains uncondensed, even at temperatures below the freezing-
point, when that vapour is distributed among some permanent gas--the
precise quantity of vapour so remaining being a function of the
temperature and barometric height. Thus it appears that if the heat
evolved during the decomposition of calcium carbide is not otherwise
consumed, it is sufficient in amount to vaporise almost exactly 3 parts
by weight of water for every 4 parts of carbide attacked; but if it were
expended upon some substance such as acetylene, calcium carbide, or
steel, which, unlike water, could not absorb an extra amount by changing
its physical state (from solid to liquid, or from liquid to gas), the
heat generated during the decomposition of a given weight of carbide
would suffice to raise an equal weight of the particular substance under
consideration to a temperature vastly exceeding 438° C. The temperature
attained, indeed, measured in Centigrade degrees, would be 438 multiplied
by the quotient obtained on dividing the specific heat of water by the
specific heat of the substance considered: which quotient, obviously, is
the "reciprocal" of the specific heat of the said substance.
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