Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and PowerLeeds, F. H. (Frank Henley)
Science
Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and Power
Leeds, F. H. (Frank Henley)
Acetylene
100.0 100.0
The average illuminating power of these mixed gases is about 126 candles
per 5 cubic feet, whereas that of pure acetylene burnt under good
laboratory conditions is 240 candles per 5 cubic feet. The product, it
will be seen, had lost almost exactly 50 per cent. of its value as an
illuminant, owing to the excessive heating to which it had been, exposed.
Some of the liquid hydrocarbons formed at the same time are not limpid
fluids like benzene, which is less viscous than water, but are thick oily
substances, or even tars. They therefore tend to block the tubes of the
apparatus with great persistence, while the tar adheres to the calcium
carbide and causes its further attack by water to be very irregular, or
even altogether impossible. In some of the very badly designed generators
of a few years back this tarry matter was distinctly visible when the
apparatus was disconnected for recharging, for the spent carbide was
exceptionally yellow, brown, or blackish in colour, [Footnote: As will be
pointed out later, the colour of the spent lime cannot always be employed
as a means for judging whether overheating has occurred in a generator.]
and the odour of tar was as noticeable as that of crude acetylene.
There is another effect of heat upon acetylene, more calculated to be
dangerous than any of those just mentioned, which must not be lost sight
of. Being an endothermic substance, acetylene is prone to decompose into
its elements--
(7) C_2H_2 -> C_2 + H_2
Public-domain text, read in full here on John Shaqi.
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