Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and PowerLeeds, F. H. (Frank Henley)
Science
Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and Power
Leeds, F. H. (Frank Henley)
Acetylene
granted that the generator is efficiently constructed, decomposition of
the carbide is absolutely complete, so that no loss of gas occurs in this
fashion; (2) the gas is evolved at a low temperature, so that it is
unaccompanied, by products of polymerisation, which may block the leading
pipes and must reduce the illuminating power; (3) the acetylene is not
mixed with air (as always happens at the first charging of a water-to-
carbide apparatus), which also lowers the illuminating power; and (4) the
gas is freed from two of its three chief impurities, viz., ammonia and
sulphuretted hydrogen, in the generating chamber itself. To prevent the
loss of acetylene by dissolution, carbide-to-water generators are
occasionally fitted with a reaction grid placed only just below the
water-level, so that the acetylene has no more than 1 inch or so of
liquid to bubble through. The principle is wrong, because hot water being
lighter than cold, the upper layers may be raised to the boiling-point,
and even converted into steam, while the bulk of the liquid still remains
cold; and if the water actually surrounding the carbide is changed into
vapour, nearly all control over the temperature attending the reaction is
lost.
The hand-fed carbide-to-water generator is very simple and, as already
indicated, has proved itself perhaps the best type of all for the
construction of very large installations; but the very simplicity of the
generator has caused it more than once to be built in a manner that has
not given entire satisfaction. As shown at L in Fig. 6, p. 84, the
generator essentially consists of a closed cylindrical vessel
communicating at its top with a separate rising holder. At one side as
drawn, or disposed concentrically if so preferred, is an open-mouthed
pipe or shoot (American "shute") having its lower open extremity below
the water-level. Into this shoot are dropped by hand or shovel lumps of
carbide, which fall into the water and there suffer decomposition. As the
bottom of the shoot is covered with water, which, owing to the small
effective gas pressure in the generator given by the holder, stands a few
inches higher in the shoot than in the generator, gas cannot escape from
the shoot; because before it could do so the water in the generator would
have to fall below the level of the point _a_, being either driven
out through the shoot or otherwise. Since the point _b_ of the shoot
extends further into the generator than _a_, the carbide drops
centrally, and as the bubbles of gas rise vertically, they have no
opportunity of ascending into the shoot. In practice, the generator is
fitted with a conical bottom for the collection of the lime sludge and
with a cock or other aperture at the apex of the cone for the removal of
the waste product. As it is not desirable that the carbide should be
allowed to fall directly from the shoot into the thicker portion of the
sludge within the conical part of the generator, one or more grids is
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