Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and PowerLeeds, F. H. (Frank Henley)
Science
Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and Power
Leeds, F. H. (Frank Henley)
Acetylene
When, however, it falls upon a grid placed some distance
above the bottom of the water vessel, the various convection currents set
up as parts of the liquid become warm, and the mechanical agitations
produced by the upward current of gas rinse the spent lime from the
carbide, and entirely prevent overheating, unless the lumps are
excessively large in size. If the carbide charged into a hand-fed
generator is in very large lumps there is always a possibility that
overheating may occur in the centre of the masses, due to the baking of
the exterior, even if the generator is fitted with a reaction grid.
Manifestly, when carbide in lumps of reasonable size is dropped into
excess of water which is not merely a thick viscid cream of lime, the
temperature cannot possibly exceed the boiling-point--_i.e._, 100°
C.--provided always the natural convection currents of the water are
properly made use of.
The defect which is, or rather which may be, characteristic of a hand-fed
carbide-to-water generator is a deficiency of gas yield due to
solubility. At atmospheric temperatures and pressure 10 volumes of water
dissolve 11 volumes of acetylene, and were the whole of the water in a
large generator run to waste often, a sensible loss of gas would ensue.
If the carbide falls nearly to the bottom of the water column, the rising
gas is forced to bubble through practically the whole of the liquid, so
that every opportunity is given it to dissolve in the manner indicated
till the liquid is completely saturated. The loss, however, is not nearly
so serious as is sometimes alleged, because (1) the water becomes heated
and so loses much of its solvent power; and (2) the generator is worked
intermittently, with sufficiently long intervals to allow the spent lime
to settle into a thick cream, and only that thick cream is run off, which
represents but a small proportion of the total water present. Moreover, a
hand-fed carbide-to-water generator will work satisfactorily with only
half a gallon [Footnote: The United States National Board of Fire
Underwriters stipulates for the presence of 1 (American) gallon of water
for every 1 lb. of carbide before such an apparatus is "permitted." This
quantity of liquid might retain nearly 4 per cent. of the total acetylene
evolved. Even this is an exaggeration; for neither her, nor in the
corresponding figure given in the text, is any allowance made for the
diminution in solvent power of the water as it becomes heated by the
reaction.] of liquid present for every 1 lb. of carbide decomposed, and
were all this water run off and a fresh quantity admitted before each
fresh introduction of carbide, the loss of acetylene by dissolution could
not exceed 2 per cent. of the total make, assuming the carbide to be
capable of yielding 5 cubic feet of gas per lb. Admitting, however, that
some loss of gas does occur in this manner, the defect is partly, if not
wholly, neutralised by the concomitant advantages of the system: (1)
Public-domain text, read in full here on John Shaqi.
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