Washington, D.C., has many buildings of historic and cultural significance, and many of them are made of marble and limestone. This self-guided tour will point out damage to buildings and monuments in our Nation’s capital that may have been caused by acid precipitation. Similar effects may be found in other cities as well. Places to visit have been divided into several areas, so the trip can be done either in segments or all in one day. A suggested tour route is described within each area. A car provides the most efficient transport between areas, but parking may be hard to find. The Metro subway system can easily be used to visit all areas except the Jefferson and Lincoln Memorials. The closest Metro stations in each area are shown on the map. You will need comfortable walking shoes, and you may want to bring along a camera, a hand lens (about 10× magnification) for observing details of minerals and weathering, and a pair of binoculars for closer examination of inaccessible areas. The area around the National Capitol This area includes the Capitol building, the Peace Monument, the Grant Memorial, and the Botanic Gardens. We begin the tour at the southeast corner of the Capitol, and go clockwise around the Capitol (along the south, west, and then north sides). We then follow a walkway heading west, from the northeast corner of the Capitol, to see the Peace Monument at the intersection of First Street and Pennsylvania Avenue, NW. We continue south along First Street to the Grant Memorial and then south again to the Botanic Gardens. Total distance is about one kilometer, or about three-quarters of a mile. The Capitol Building—Site 1 The Capitol was built in stages; the cornerstone of the main building was laid in 1793, the north wing was completed in 1800, and the south wing was completed in 1807. Both wings were burned by the British in 1814. The capitol was then rebuilt, and it has been modified several times throughout the years. A major program of cleaning, replacement, and repair was begun in the late 1980’s. The center building of the Capitol is painted sandstone, but the north and south wings, housing the Senate and the House chambers, are marble. Around the Capitol we will observe various examples of dissolution and blackened alteration, especially on the marble balustrade that surrounds the south, west, and north sides of the building.