An Elementary Study of ChemistryMcPherson, William
Science
An Elementary Study of Chemistry
McPherson, William
Chemistry
Not only can sulphuric acid absorb water, but it will often withdraw the
elements hydrogen and oxygen from a compound containing them,
decomposing the compound, and combining with the water so formed. For
this reason most organic substances, such as sugar, wood, cotton, and
woolen fiber, and even flesh, all of which contain much oxygen and
hydrogen in addition to carbon, are charred or burned by the action of
the concentrated acid.
~Salts of sulphuric acid,--sulphates.~ The sulphates form a very important
class of salts, and many of them have commercial uses. Copperas (iron
sulphate), blue vitriol (copper sulphate), and Epsom salt (magnesium
sulphate) serve as examples. Many sulphates are important minerals,
prominent among these being gypsum (calcium sulphate) and barytes
(barium sulphate).
~Thiosulphuric acid~ (H_{2}S_{2}O_{3}); ~Thiosulphates.~ Many other
acids of sulphur containing oxygen are known, but none of them
are of great importance. Most of them cannot be prepared in a
pure state, and are known only through their salts. The most
important of these is thiosulphuric acid.
When sodium sulphite is boiled with sulphur the two substances
combine, forming a salt which has the composition represented
in the formula Na_{2}S_{2}O_{3}:
Na_{2}SO_{3} + S = Na_{2}S_{2}O_{3}.
The substance is called sodium thiosulphate, and is a salt of
the easily decomposed acid H_{2}S_{2}O_{3}, called
thiosulphuric acid. This reaction is quite similar to the
action of oxygen upon sulphites:
Na_{2}SO_{3} + O = Na_{2}SO_{4}.
More commonly the salt is called sodium hyposulphite, or merely
"hypo." It is a white solid and is extensively used in
photography, in the bleaching industry, and as a disinfectant.
~Monobasic and dibasic acids.~ Such acids as hydrochloric and nitric
acids, which have only one replaceable hydrogen atom in the molecule, or
in other words yield one hydrogen ion in solution, are called monobasic
acids. Acids yielding two hydrogen ions in solution are called dibasic
acids. Similarly, we may have tribasic and tetrabasic acids. The three
acids of sulphur are dibasic acids. It is therefore possible for each of
them to form both normal and acid salts. The acid salts can be made in
two ways: the acid may be treated with only half enough base to
neutralize it,--
NaOH + H_{2}SO_{4} = NaHSO_{4} + H_{2}O;
or a normal salt may be treated with the free acid,--
Na_{2}SO_{4} + H_{2}SO_{4} = 2NaHSO_{4}.
Acid sulphites and sulphides may be made in the same ways.
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