An Elementary Study of ChemistryMcPherson, William
Science
An Elementary Study of Chemistry
McPherson, William
Chemistry
~Carbon disulphide~ (CS_{2}). When sulphur vapor is passed over highly
heated carbon the two elements combine, forming carbon disulphide
(CS_{2}), just as oxygen and carbon unite to form carbon dioxide
(CO_{2}). The substance is a heavy, colorless liquid, possessing, when
pure, a pleasant ethereal odor. On standing for some time, especially
when exposed to sunlight, it undergoes a slight decomposition and
acquires a most disagreeable, rancid odor. It has the property of
dissolving many substances, such as gums, resins, and waxes, which are
insoluble in most liquids, and it is extensively used as a solvent for
such substances. It is also used as an insecticide. It boils at a low
temperature (46 deg.), and its vapor is very inflammable, burning in the air
to form carbon dioxide and sulphur dioxide, according to the equation
CS_{2} + 6O = CO_{2} + 2SO_{2}.
[Illustration: Fig. 45]
~Commercial preparation of carbon disulphide.~ In the preparation
of carbon disulphide an electrical furnace is employed, such as
is represented in Fig. 45. The furnace is packed with carbon
C, and this is fed in through the hoppers B, as fast as
that which is present in the hearth of the furnace is used up.
Sulphur is introduced at A, and at the lower ends of the
tubes it is melted by the heat of the furnace and flows into
the hearth as a liquid. An electrical current is passed through
the carbon and melted sulphur from the electrodes E, heating
the charge. The vapors of carbon disulphide pass up through the
furnace and escape at D, from which they pass to a suitable
condensing apparatus.
~Comparison of sulphur and oxygen.~ A comparison of the formulas and the
chemical properties of corresponding compounds of oxygen and sulphur
brings to light many striking similarities. The conduct of
hydrosulphuric acid and water toward many substances has been seen to be
very similar; the oxides and sulphides of the metals have analogous
formulas and undergo many parallel reactions. Carbon dioxide and
disulphide are prepared in similar ways and undergo many analogous
reactions. It is clear, therefore, that these two elements are far more
closely related to each other than to any of the other elements so far
studied.
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