An Elementary Study of ChemistryMcPherson, William
Science
An Elementary Study of Chemistry
McPherson, William
Chemistry
~Selenium and tellurium.~ These two very uncommon elements are still more
closely related to sulphur than is oxygen. They occur in comparatively
small quantities and are usually found associated with sulphur and
sulphides, either as the free elements or more commonly in combination
with metals. They form compounds with hydrogen of the formulas H_{2}Se
and H_{2}Te; these bodies are gases with properties very similar to
those of H_{2}S. They also form oxides and oxygen acids which resemble
the corresponding sulphur compounds. The elements even have allotropic
forms corresponding very closely to those of sulphur. Tellurium is
sometimes found in combination with gold and copper, and occasions some
difficulties in the refining of these metals. The elements have very few
practical applications.
~Crystallography.~ In order to understand the difference between the two
kinds of sulphur crystals, it is necessary to know something about
crystals in general and the forms which they may assume. An examination
of a large number of crystals has shown that although they may differ
much in geometric form, they can all be considered as modifications of a
few simple plans. The best way to understand the relation of one crystal
to another is to look upon every crystal as having its faces and angles
arranged in definite fashion about certain imaginary lines drawn
through the crystal. These lines are called axes, and bear much the same
relation to a crystal as do the axis and parallels of latitude and
longitude to the earth and a geographical study of it. All crystals can
be referred to one of six simple plans or systems, which have their axes
as shown in the following drawings.
The names and characteristics of these systems are as follows:
1. Isometric or regular system (Fig. 46). Three equal axes, all at right
angles.
[Illustration: Fig. 46]
2. Tetragonal system (Fig. 47). Two equal axes and one of different
length, all at right angles to each other.
[Illustration: Fig. 47]
3. Orthorhombic system (Fig. 48). Three unequal axes, all at right
angles to each other.
[Illustration: Fig. 48]
4. Monoclinic system (Fig. 49). Two axes at right angles, and a third at
right angles to one of these, but inclined to the other.
[Illustration: Fig. 49]
5. Triclinic system (Fig. 50). Three axes, all inclined to each other.
[Illustration: Fig. 50]
6. Hexagonal system (Fig. 51). Three equal axes in the same plane
intersecting at angles of 60 deg., and a fourth at right angles to all of
these.
[Illustration: Fig. 51]
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