An Elementary Study of ChemistryMcPherson, William
Science
An Elementary Study of Chemistry
McPherson, William
Chemistry
1. _Action on metals._ A great many metals combine directly with
chlorine, especially when hot. A strip of copper foil heated in a burner
flame and then dropped into chlorine burns with incandescence. Sodium
burns brilliantly when heated strongly in slightly moist chlorine. Gold
and silver are quickly tarnished by the gas.
2. _Action on non-metals._ Chlorine has likewise a strong affinity for
many of the non-metals. Thus phosphorus burns in a current of the gas,
while antimony and arsenic in the form of a fine powder at once burst
into flame when dropped into jars of the gas. The products formed in all
cases where chlorine combines with another element are called
_chlorides_.
3. _Action on hydrogen._ Chlorine has a strong affinity for hydrogen,
uniting with it to form hydrochloric acid. A jet of hydrogen burning in
the air continues to burn when introduced into a jar of chlorine, giving
a somewhat luminous flame. A mixture of the two gases explodes violently
when a spark is passed through it or when it is exposed to bright
sunlight. In the latter case it is the light and not the heat which
starts the action.
4. _Action on substances containing hydrogen._ Not only will chlorine
combine directly with free hydrogen but it will often abstract the
element from its compounds. Thus, when chlorine is passed into a
solution containing hydrosulphuric acid, sulphur is precipitated and
Hydrochloric acid formed. The reaction is shown by the following
equation:
H_{2}S + 2Cl = 2HCl + S.
With ammonia the action is similar:
NH_{3} + 3Cl = 3HCl + N.
The same tendency is very strikingly seen in the action of chlorine upon
turpentine. The latter substance is largely made up of compounds having
the composition represented by the formula C_{10}H_{16}. When a strip of
paper moistened with warm turpentine is placed in a jar of chlorine
dense fumes of hydrochloric acid appear and a black deposit of carbon is
formed. Even water, which is a very stable compound, can be decomposed
by chlorine, the oxygen being liberated. This may be shown in the
following way:
[Illustration: Fig. 54]
If a long tube of rather large diameter is filled with a strong
solution of chlorine in water and inverted in a vessel of the
same solution, as shown in Fig. 54, and the apparatus is placed
in bright sunlight, very soon bubbles of a gas will be observed
to rise through the solution and collect in the tube. An
examination of this gas will show that it is oxygen. It is
liberated from water in accordance with the following equation:
H_{2}O + 2Cl = 2HCl + O.
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