An Elementary Study of ChemistryMcPherson, William
Science
An Elementary Study of Chemistry
McPherson, William
Chemistry
5. _Action on color substances,--bleaching action._ If strips of
brightly colored cloth or some highly colored flowers are placed in
quite dry chlorine, no marked change in color is noticed as a rule. If,
however, the cloth and flowers are first moistened, the color rapidly
disappears, that is, the objects are bleached. Evidently the moisture as
well as the chlorine is concerned in the action, and a study of the case
shows that the chlorine has combined with the hydrogen of the water. The
oxygen set free oxidizes the color substance, converting it into a
colorless compound. It is evident from this explanation that chlorine
will only bleach those substances which are changed into colorless
compounds by oxidation.
6. _Action as a disinfectant._ Chlorine has also marked germicidal
properties, and the free element, as well as compounds from which it is
easily liberated, are used as disinfectants.
~Nascent state.~ It will be noticed that oxygen when set free from water
by chlorine is able to do what ordinary oxygen cannot do, for both the
cloth and the flowers are unchanged in the air which contains oxygen. It
is generally true that the activity of an element is greatest at the
instant of liberation from its compounds. To express this fact elements
at the instant of liberation are said to be in the _nascent state_. It
is nascent oxygen which does the bleaching.
~Hydrochloric acid~ (_muriatic acid_) (HCl). The preparation of
hydrochloric acid may be discussed under two general heads:
1. _Laboratory preparation._ The product formed by the burning of
hydrogen in chlorine is the gas hydrochloric acid. This substance is
much more easily obtained, however, by treating common salt (sodium
chloride) with sulphuric acid. The following equation shows the
reaction:
2NaCl + H_{2}SO_{4} = Na_{2}SO_{4} + 2HCl.
The dry salt is placed in a flask furnished with a funnel tube and an
exit tube, the sulphuric acid is added, and the flask gently warmed. The
hydrochloric acid gas is rapidly given off and can be collected by
displacement of air. The same apparatus can be used as was employed in
the preparation of chlorine (Fig. 53).
When a _solution_ of salt is treated with sulphuric acid there
is no very marked action. The hydrochloric acid formed is very
soluble in water, and so does not escape from the solution;
hence a state of equilibrium is soon reached between the four
substances represented in the equation. When _concentrated_
sulphuric acid, in which hydrochloric acid is not soluble, is
poured upon dry salt the reaction is complete.
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