An Elementary Study of ChemistryMcPherson, William
Science
An Elementary Study of Chemistry
McPherson, William
Chemistry
Many ores other than oxides may be changed into oxides which can then be
reduced by carbon. The conversion of such ores into oxides is generally
accomplished by heating, and this process is called _roasting_. Many
carbonates and hydroxides decompose directly into the oxide on heating.
Sulphides, on the other hand, must be heated in a current of air, the
oxygen of the air entering into the reaction. The following equations
will serve to illustrate these changes in the case of the ores of iron:
FeCO_{3} = FeO + CO_{2},
2Fe(OH)_{3} = Fe_{2}O_{3} + 3H_{2}O,
2FeS_{2} + 11O = Fe_{2}O_{3} + 4SO_{2}.
2. _Reduction of an oxide with aluminium._ Not all oxides, however, can
be reduced by carbon. In such cases aluminium may be used. Thus chromium
may be obtained in accordance with the following equation:
Cr_{2}O_{3} + 2 Al = 2 Cr + Al_{2}O_{3}.
This method is a comparatively new one, having been brought into use by
the German chemist Goldschmidt; hence it is sometimes called the
Goldschmidt method.
3. _Electrolysis._ In recent years increasing use is being made of the
electric current in the preparation of metals. In some cases the
separation of the metal from its compounds is accomplished by passing
the current through a solution of a suitable salt of the metal, the
metal usually being deposited upon the cathode. In other cases the
current is passed through a fused salt of the metal, the chloride being
best adapted to this purpose.
~Electro-chemical industries.~ Most of the electro-chemical industries of
the country are carried on where water power is abundant, since this
furnishes the cheapest means for the generation of electrical energy.
Niagara Falls is the most important locality in this country for such
industries, and many different electro-chemical products are
manufactured there. Some industries depend upon electrolytic processes,
while in others the electrical energy is used merely as a source of heat
in electric furnaces.
~Preparation of compounds of the metals.~ Since the compounds of the
metals are so numerous and varied in character, there are many ways of
preparing them. In many cases the properties of the substance to be
prepared, or the material available for its preparation, suggest a
rather unusual way. There are, however, a number of general principles
which are constantly applied in the preparation of the compounds of the
metals, and a clear understanding of them will save much time and effort
in remembering the details in any given case. The most important of
these general methods for the preparation of compounds are the
following:
1. _By direct union of two elements._ This is usually accomplished by
heating the two elements together. Thus the sulphides, chlorides, and
oxides of a metal can generally be obtained in this way. The following
equations serve as examples of this method:
Fe + S = FeS,
Mg + O = MgO,
Cu + 2Cl = CuCl_{2}.
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