An Elementary Study of ChemistryMcPherson, William
Science
An Elementary Study of Chemistry
McPherson, William
Chemistry
~Preparation.~ When electric sparks are passed through oxygen or air a
small percentage of the oxygen is converted into a substance called
_ozone_, which differs greatly from oxygen in its properties. The same
change can also be brought about by certain chemical processes. Thus, if
some pieces of phosphorus are placed in a bottle and partially covered
with water, the presence of ozone may soon be detected in the air
contained in the bottle. The conversion of oxygen into ozone is attended
by a change in volume, 3 volumes of oxygen forming 2 volumes of ozone.
If the resulting ozone is heated to about 300 deg., the reverse change
takes place, the 2 volumes of ozone being changed back into 3 volumes of
oxygen. It is possible that traces of ozone exist in the atmosphere,
although its presence there has not been definitely proved, the tests
formerly used for its detection having been shown to be unreliable.
~Properties.~ As commonly prepared, ozone is mixed with a large excess of
oxygen. It is possible, however, to separate the ozone and thus obtain
it in pure form. The gas so obtained has the characteristic odor noticed
about electrical machines when in operation. By subjecting it to great
pressure and a low temperature, the gas condenses to a bluish liquid,
boiling at -119 deg.. When unmixed with other gases ozone is very explosive,
changing back into oxygen with the liberation of heat. Its chemical
properties are similar to those of oxygen except that it is far more
active. Air or oxygen containing a small amount of ozone is now used in
place of oxygen in certain manufacturing processes.
~The difference between oxygen and ozone.~ Experiments show that in
changing oxygen into ozone no other kind of matter is either added to
the oxygen or withdrawn from it. The question arises then, How can we
account for the difference in their properties? It must be remembered
that in all changes we have to take into account _energy_ as well as
_matter_. By changing the amount of energy in a substance we change its
properties. That oxygen and ozone contain different amounts of energy
may be shown in a number of ways; for example, by the fact that the
conversion of ozone into oxygen is attended by the liberation of heat.
The passage of the electric sparks through oxygen has in some way
changed the energy content of the element and thus it has acquired new
properties. _Oxygen and ozone must, therefore, be regarded as identical
so far as the kind of matter of which they are composed is concerned.
Their different properties are due to their different energy contents._
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