An Elementary Study of ChemistryMcPherson, William
Science
An Elementary Study of Chemistry
McPherson, William
Chemistry
~Uses of aluminium.~ These properties suggest many uses for the metal. Its
lightness, strength, and permanence make it well adapted for many
construction purposes. These same properties have led to its extensive
use in the manufacture of cooking utensils. The fact that it is easily
corroded by salt solutions is, however, a disadvantage. Owing to its
small resistance to electrical currents, it is replacing copper to some
extent in electrical construction, especially for trolley and power
wires. Some of its alloys have very valuable properties, and a
considerable part of the aluminium manufactured is used for this
purpose. Aluminium bronze, consisting of about 90% copper and 10%
aluminium, has a pure golden color, is strong and malleable, is easily
cast, and is permanent in the air. Considerable amounts of aluminium
steel are also made.
~Goldschmidt reduction process.~ Aluminium is frequently employed as a
powerful reducing agent, many metallic oxides which resist reduction by
carbon being readily reduced by it. The aluminium in the form of a fine
powder is mixed with the metallic oxide, together with some substance
such as fluorspar to act as a flux. The mixture is ignited, and the
aluminium unites with the oxygen of the metallic oxide, liberating the
metal. This collects in a fused condition under the flux.
An enormous quantity of heat is liberated in this reaction, and a
temperature as high as 3500 deg. can be reached. The heat of the reaction is
turned to practical account in welding car rails, steel castings, and in
similar operations where an intense local heat is required. A mixture of
aluminium with various metallic oxides, ready prepared for such
purposes, is sold under the name of _thermite_.
[Illustration: Fig. 83]
~Preparation of chromium by the Goldschmidt method.~ A mixture of
chromium oxide and aluminium powder is placed in a Hessian
crucible (A, Fig. 83), and on top of it is placed a small
heap B of a mixture of sodium peroxide and aluminium, into
which is stuck a piece of magnesium ribbon C. Powdered
fluorspar D is placed around the sodium peroxide, after which
the crucible is set on a pan of sand and the magnesium ribbon
ignited. When the flame reaches the sodium peroxide mixture
combustion of the aluminium begins with almost explosive
violence, so that great care must be taken in the experiment.
The heat of this combustion starts the reaction in the chromium
oxide mixture, and the oxide is reduced to metallic chromium.
When the crucible has cooled a button of chromium will be found
in the bottom.
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