An Elementary Study of ChemistryMcPherson, William
Science
An Elementary Study of Chemistry
McPherson, William
Chemistry
~Aluminium oxide~ (Al_{2}O_{3}). This substance occurs in several forms in
nature. The relatively pure crystals are called corundum, while emery is
a variety colored dark gray or black, usually with iron compounds. In
transparent crystals, tinted different colors by traces of impurities,
it forms such precious stones as the sapphire, oriental ruby, topaz, and
amethyst. All these varieties are very hard, falling little short of
the diamond in this respect. Chemically pure aluminium oxide can be made
by igniting the hydroxide, when it forms an amorphous white powder:
2Al(OH)_{3} = Al_{2}O_{3} + 3H_{2}O.
The natural varieties, corundum and emery, are used for cutting and
grinding purposes; the purest forms, together with the artificially
prepared oxide, are largely used in the preparation of aluminium.
~Aluminium hydroxide~ (Al(OH)_{3}). The hydroxide occurs in nature as the
mineral hydrargyllite, and in a partially dehydrated form called
bauxite. It can be prepared by adding ammonium hydroxide to any soluble
aluminium salt, forming a semi-transparent precipitate which is
insoluble in water but very hard to filter. It dissolves in most acids
to form soluble salts, and in the strong bases to form aluminates, as
indicated in the equations
Al(OH)_{3} + 3HCl = AlCl_{3} + 3H_{2}O,
Al(OH)_{3} + 3NaOH = Al(ONa)_{3} + 3H_{2}O.
It may act, therefore, either as a weak base or as a weak acid, its
action depending upon the character of the substances with which it is
in contact. When heated gently the hydroxide loses part of its hydrogen
and oxygen according to the equation
Al(OH)_{3} = AlO.OH + H_{2}O.
This substance, the formula of which is frequently written HAlO_{2}, is
a more pronounced acid than is the hydroxide, and its salts are
frequently formed when aluminium compounds are fused with alkalis. The
magnesium salt Mg(AlO_{2})_{2} is called spinel, and many other of its
salts, called aluminates, are found in nature.
When heated strongly the hydroxide is changed into oxide, which will not
again take up water on being moistened.
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