An Elementary Study of ChemistryMcPherson, William
Science
An Elementary Study of Chemistry
McPherson, William
Chemistry
~Ceramic industries.~ Many articles of greatest practical
importance, ranging from the roughest brick and tile to the
finest porcelain and chinaware, are made from some form of
kaolin, or clay. No very precise classification of such ware
can be made, as the products vary greatly in properties,
depending upon the materials used and the treatment during
manufacture.
Porcelain is made from the purest kaolin, to which must be
added some less pure, plastic kaolin, since the pure substance
is not sufficiently plastic. There is also added some more
fusible substance, such as feldspar, gypsum, or lime, together
with some pure quartz. The constituents must be ground very
fine, and when thoroughly mixed and moistened must make a
plastic mass which can be molded into any desired form. The
article molded from such materials is then burned. In this
process the article is slowly heated to a point at which it
begins to soften and almost fuse, and then it is allowed to
cool slowly. At this stage, a very thin vessel will be
translucent and have an almost glassy fracture; if, however, it
is somewhat thicker, or has not been heated quite so high, it
will still be porous, and partly on this account and partly to
improve its appearance it is usually glazed.
Glazing is accomplished by spreading upon the object a thin
layer of a more fusible mixture of the same materials as
compose the body of the object itself, and again heating until
the glaze melts to a transparent glassy coating upon the
surface of the vessel. In some cases fusible mixtures of quite
different composition from that used in fashioning the vessel
may be used as a glaze. Oxides of lead, zinc, and barium are
often used in this way.
When less carefully selected materials are used, or quite thick
vessels are made, various grades of stoneware are produced. The
inferior grades are glazed by throwing a quantity of common
salt into the kiln towards the end of the first firing. In the
form of vapor the salt attacks the surface of the baked ware
and forms an easily fusible sodium silicate upon it, which
constitutes a glaze.
Vitrified bricks, made from clay or ground shale, are burned
until the materials begin to fuse superficially, forming their
own glaze. Other forms of brick and tile are not glazed at all,
but are left porous. The red color of ordinary brick and
earthenware is due to an oxide of iron formed in the burning
process.
The decorations upon china are sometimes painted upon the baked
ware and then glazed over, and sometimes painted upon the glaze
and burned in by a third firing. Care must be taken to use such
pigments as are not affected by a high heat and do not react
chemically with the constituents of the baked ware or the
glaze.
EXERCISES
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