An Elementary Study of ChemistryMcPherson, William
Science
An Elementary Study of Chemistry
McPherson, William
Chemistry
~Uses.~ Copper is extensively used for electrical purposes, for roofs and
cornices, for sheathing the bottom of ships, and for making alloys. In
the following table the composition of some of these alloys is
indicated:
COMPOSITION OF ALLOYS OF COPPER IN PERCENTAGES
Aluminium bronze copper (90 to 97%), aluminium (3 to 10%).
Brass copper (63 to 73%), zinc (27 to 37%).
Bronze copper (70 to 95%), zinc (1 to 25%), tin (1 to 18%).
German silver copper (56 to 60%), zinc (20%), nickel (20 to 25%).
Gold coin copper (10%), gold (90%).
Gun metal copper (90%), tin (10%).
Nickel coin copper (75%), nickel (25%)
Silver coin copper (10%), silver (90%).
~Electrotyping.~ Matter is often printed from electrotype plates
which are prepared as follows. The matter is set up in type and
wax is firmly pressed down upon the face of it until a clear
impression is obtained. The impressed side of the wax is coated
with graphite and the impression is made the cathode in an
electrolytic cell containing a copper salt in solution. When
connected with a current the copper is deposited as a thin
sheet upon the letters in wax, and when detached is a perfect
copy of the type, the under part of the letters being hollow.
The sheet is strengthened by pouring on the under surface a
suitable amount of molten metal (commercial lead is used). The
sheet so strengthened is then used in printing.
~Two series of copper compounds.~ Copper, like iron, forms two series of
compounds: in the cuprous compounds it is univalent; in the cupric it is
divalent. The cupric salts are much the more common of the two, since
the cuprous salts pass readily into cupric by oxidation.
~Cuprous compounds.~ The most important cuprous compound is the oxide
(Cu_{2}O), which occurs in nature as ruby copper or cuprite. It is a
bright red substance and can easily be prepared by heating copper to a
high temperature in a limited supply of air. It is used for imparting a
ruby color to glass.
By treating cuprous oxide with different acids a number of cuprous salts
can be made. Many of these are insoluble in water, the chloride (CuCl)
being the best known. When suspended in dilute hydrochloric acid it is
changed into cupric chloride, the oxygen taking part in the reaction
being absorbed from the air:
2CuCl + 2HCl + O = 2CuCl_{2} + H_{2}O.
~Cupric compounds.~ Cupric salts are easily made by dissolving cupric
oxide in acids, or, when insoluble, by precipitation. Most of them are
blue or green in color, and the soluble ones crystallize well. Since
they are so much more familiar than the cuprous salts, they are
frequently called merely copper salts.
~Cupric oxide~ (CuO). This is a black insoluble substance obtained by
heating copper in excess of air, or by igniting the hydroxide or
nitrate. It is used as an oxidizing agent.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account