An Elementary Study of ChemistryMcPherson, William
Science
An Elementary Study of Chemistry
McPherson, William
Chemistry
~The grouping of compounds in classes.~ The study of organic chemistry is
much simplified by the fact that the large number of bodies included in
this field may be grouped in classes of similar compounds. It thus
becomes possible to study the properties of each class as a whole, in
much the same way as we study a group of elements. The most important of
these classes are the _hydrocarbons_, the _alcohols_, the _aldehydes_,
the _acids_, the _ethereal salts_, the _ethers_, the _ketones_, the
_organic bases_, and the _carbohydrates_. A few members of each of these
classes will now be discussed briefly.
THE HYDROCARBONS
Carbon and hydrogen combine to form a large number of compounds. These
compounds are known collectively as the _hydrocarbons_. They may be
divided into a number of groups or series, each being named from its
first member. Some of the groups are as follows:
METHANE SERIES
CH_{4} methane
C_{2}H_{6} ethane
C_{3}H_{8} propane
C_{4}H_{10} butane
C_{5}H_{12} pentane
C_{6}H_{14} hexane
C_{7}H_{16} heptane
C_{8}H_{18} octane
ETHYLENE SERIES
C_{2}H_{4} ethylene
C_{3}H_{6} propylene
C_{4}H_{8} butylene
BENZENE SERIES
C_{6}H_{6} benzene
C_{7}H_{8} toluene
C_{8}H_{10} xylene
ACETYLENE SERIES
C_{2}H_{2} acetylene
C_{3}H_{4} allylene
Only the lower members (that is, those which contain a small number of
carbon atoms) of the above groups are given. The methane series is the
most extensive, all of the compounds up to C_{24}H_{50} being known.
It will be noticed that the successive members of each of the above
series differ by the group of atoms (CH_{2}). Such a series is called an
_homologous series_. In general, it may be stated that the members of an
homologous series show a regular gradation in most physical properties
and are similar in chemical properties. Thus in the methane group the
first four members are gases at ordinary temperatures; those containing
from five to sixteen carbon atoms are liquids, the boiling points of
which increase with the number of carbon atoms present. Those containing
more than sixteen carbon atoms are solids.
~Sources of the hydrocarbons.~ There are two chief sources of the
hydrocarbons, namely, (1) crude petroleum and (2) coal tar.
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