An Elementary Study of ChemistryMcPherson, William
Science
An Elementary Study of Chemistry
McPherson, William
Chemistry
The resulting compounds of which methyl nitrate (CH_{3}NO_{3}) may be
taken as the type belong to the class known as _ethereal salts_, the
name having been given them because some of them possess pleasant
ethereal odors. It will be seen that the ethereal salts differ from
ordinary salts in that they contain a hydrocarbon radical, such as
CH_{3}, C_{2}H_{5}, C_{3}H_{5}, in place of a metal.
~The nitrates of glycerin~ (_nitroglycerin_). Nitric acid reacts with
glycerin in the same way that it reacts with a base containing three
hydroxyl groups such as Fe(OH)_{3}:
Fe(OH)_{3} + 3HNO_{3} = Fe(NO_{3})_{3} + 3H_{2}O,
C_{3}H_{5}(OH)_{3} + 3HNO_{3} = C_{3}H_{5}(NO_{3})_{3} + 3H_{2}O.
The resulting nitrate (C_{3}H_{5}(NO_{3})_{3}) is the main constituent
of _nitroglycerin_, a slightly yellowish oil characterized by its
explosive properties. Dynamite consists of porous earth which has
absorbed nitroglycerin, and its strength depends on the amount present.
It is used much more largely than nitroglycerin itself, since it does
not explode so readily by concussion and hence can be transported with
safety.
~The fats.~ These are largely mixtures of the ethereal salts known
respectively as olein, palmitin, and stearin. These salts may be
regarded as derived from oleic, palmitic, and stearic acids
respectively, by replacing the hydrogen of the acid with the glycerin
radical C_{3}H_{5}. Since this radical is trivalent and oleic, palmitic,
and stearic acids contain only one replaceable hydrogen atom to the
molecule, it is evident that three molecules of each acid must enter
into each molecule of the ethereal salt. The formulas for the acids and
the ethereal salts derived from each are as follows:
HC_{18}H_{33}O_{2} (oleic acid)
C_{8}H_{6}(C_{18}H_{33}O_{2})_{3}, (olein)
HC_{16}H_{31}O_{2} (palmitic acid)
C_{3}H_{5}(C_{16}H_{31}0_{2})_{3} (palmitin)
HC_{18}H_{35}O_{2} (stearic acid)
C_{3}H_{5}(C_{18}H_{35}O_{2})_{3} (stearin)
Olein is a liquid and is the main constituent of liquid fats. Palmitin
and stearin are solids.
~Butter fat and oleomargarine.~ Butter fat consists principally of olein,
palmitin, and stearin. The flavor of the fat is due to the presence of a
small amount of butyrin, which is an ethereal salt of butyric acid.
Oleomargarine differs from butter mainly in the fact that a smaller
amount of butyrin is present. It is made from the fats obtained from
cattle and hogs. This fat is churned up with milk, or a small amount of
butter is added, in order to furnish sufficient butyrin to impart the
butter flavor.
~Saponification.~ When an ethereal salt is heated with an alkali a
reaction expressed by the following equation takes place:
C_{2}H_{5}NO_{3} + KOH = C_{2}H_{5}OH + KNO_{3}.
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