An Elementary Study of ChemistryMcPherson, William
Science
An Elementary Study of Chemistry
McPherson, William
Chemistry
This process is known as _saponification_, since it is the one which
takes place in the manufacture of soaps. The ordinary soaps are made by
heating fats with a solution of sodium hydroxide. The reactions
involved may be illustrated by the following equation representing the
reaction between palmitin and sodium hydroxide:
C_{3}H_{5}(C_{16}H_{31}O_{2})_{3} + 3 NaOH
= 3 NaC_{16}H_{31}O_{2} + C_{3}H_{5}(OH)_{3}.
In accordance with this equation the ethereal salts in the fats are
converted into glycerin and the sodium salts of the corresponding acids.
The sodium salts are separated and constitute the soaps. These salts are
soluble in water. When added to water containing calcium salts the
insoluble calcium palmitate and stearate are precipitated. Magnesium
salts act in a similar way. It is because of these facts that soap is
used up by hard waters.
ETHERS
When ethyl alcohol is heated to 140 deg. with sulphuric acid the reaction
expressed by the following equation takes place:
2C_{2}H_{5}OH = (C_{2}H_{5})_{2}O + H_{2}O.
The resulting compound, (C_{2}H_{5})_{2}O, is ordinary ether and is the
most important member of the class of compounds called _ethers_.
Ordinarily ether is a light, very inflammable liquid boiling at 35 deg.. It
is used as a solvent for organic substances and as an anaesthetic in
surgical operations.
KETONES
The most common member of this group is acetone (C_{3}H_{6}O), a
colorless liquid obtained when wood is heated in the absence of air. It
is used in the preparation of other organic compounds, especially
chloroform.
ORGANIC BASES
This group includes a number of compounds, all of which contain nitrogen
as well as carbon. They are characterized by combining directly with
acids to form salts, and in this respect they resemble ammonia. They
may, indeed, be regarded as derived from ammonia by displacing a part or
all of the hydrogen present in ammonia by hydrocarbon radicals. Among
the simplest of these compounds may be mentioned methylamine
(CH_{3}NH_{2}) and ethylamine (C_{2}H_{5}NH_{2}). These two compounds
are gases and are formed in the distillation of wood and bones. Pyridine
(C_{5}H_{6}N) and quinoline (C_{9}H_{7}N) are liquids present in small
amounts in coal tar, and also in the liquid obtained by the distillation
of bones. Most of the compounds now classified under the general name of
_alkaloids_ (which see) also belong to this group.
CARBOHYDRATES
The term "carbohydrate" is applied to a class of compounds which
includes the sugars, starch, and allied bodies These compounds contain
carbon, hydrogen, and oxygen the last two elements generally being
present in the proportion in which they combine to form water. The most
important members of this class are the following:
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