An Elementary Study of ChemistryMcPherson, William
Science
An Elementary Study of Chemistry
McPherson, William
Chemistry
~Reduction.~ On account of its great affinity for oxygen, hydrogen has the
power of abstracting it from many of its compounds. Thus, if a stream of
hydrogen, dried by passing through the tube B (Fig. 15), filled with
calcium chloride, is conducted through the tube C containing some
copper oxide, heated to a moderate temperature, the hydrogen abstracts
the oxygen from the copper oxide. The change may be represented as
follows:
hydrogen + {copper} {hydrogen}
{oxygen}(copper oxide) = {oxygen }(water) + copper
The water formed collects in the cold portions of the tube C near its
end. In this experiment the copper oxide is said to undergo reduction.
_Reduction may therefore be defined as the process of withdrawing oxygen
from a compound._
~Relation of reduction to oxidation.~ At the same time that the copper
oxide is reduced it is clear that the hydrogen is oxidized, for it
combines with the oxygen given up by the copper oxide. The two processes
are therefore very closely related, and it usually happens that when one
substance is oxidized some other substance is reduced. That substance
which gives up its oxygen is called an _oxidizing agent_, while the
substance which unites with the oxygen is called a _reducing agent_.
~The oxyhydrogen blowpipe.~ This is a form of apparatus used for burning
hydrogen in pure oxygen. As has been previously stated, the flame
produced by the combustion of hydrogen in the air is very hot. It is
evident that if pure oxygen is substituted for air, the temperature
reached will be much higher, since there are no inert gases to absorb
the heat. The oxyhydrogen blowpipe, used to effect this combination,
consists of a small tube placed within a larger one, as shown in Fig.
16.
[Illustration: Fig. 16]
The hydrogen, stored under pressure, generally in steel cylinders, is
first passed through the outer tube and ignited at the open end of the
tube. The oxygen from a similar cylinder is then conducted through the
inner tube, and mixes with the hydrogen at the end of the tube. In order
to produce the maximum heat, the hydrogen and oxygen must be admitted to
the blowpipe in the exact proportion in which they combine, viz., 2
volumes of hydrogen to 1 of oxygen, or by weight, 1 part of hydrogen to
7.94 parts of oxygen. The intensity of the heat may be shown by bringing
into the flame pieces of metal such as iron wire or zinc. These burn
with great brilliancy. Even platinum, having a melting point of 1779 deg.,
may be melted by the heat of the flame.
While the oxyhydrogen flame is intensely hot, it is almost non-luminous.
If directed against some infusible substance like ordinary lime (calcium
oxide), the heat is so intense that the lime becomes incandescent and
glows with a brilliant light. This is sometimes used as a source of
light, under the name of _Drummond_ or _lime light_.
[Illustration: Fig. 17]
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