An Elementary Study of ChemistryMcPherson, William
Science
An Elementary Study of Chemistry
McPherson, William
Chemistry
1. _Qualitative analysis._ As was stated in the study of oxygen, water
may be separated into its component parts by means of the electric
current. The form of apparatus ordinarily used for effecting this
analysis is shown in Fig. 18. A platinum wire, to the end of which is
attached a small piece of platinum foil (about 15 mm. by 25 mm.), is
fused through each of the tubes B and D, as shown in the figure. The
stopcocks at the ends of these tubes are opened and water, to which has
been added about one tenth of its volume of sulphuric acid, is poured
into the tube A until the side tubes B and D are completely
filled. The stopcocks are then closed. The platinum wires extending into
the tubes B and D are now connected with the wires leading from two
or three dichromate cells joined in series. The pieces of platinum foil
within the tubes thus become the electrodes, and the current flows from
one to the other through the acidulated water. As soon as the current
passes, bubbles of gas rise from each of the electrodes and collect in
the upper part of the tubes. The gas rising from the negative electrode
is found to be hydrogen, while that from the positive electrode is
oxygen. It will be seen that the volume of the hydrogen is approximately
double that of the oxygen. Oxygen is more soluble in water than
hydrogen, and a very little of it is also lost by being converted into
ozone and other substances. It has been found that when the necessary
corrections are made for the error due to these facts, the volume of the
hydrogen is exactly double that of the oxygen.
Fig. 19 illustrates a simpler form of apparatus, which may be used in
place of that shown in Fig. 18. A glass or porcelain dish is partially
filled with water to which has been added the proper amount of acid. Two
tubes filled with the same liquid are inverted over the electrodes. The
gases resulting from the decomposition of the water collect in the
tubes.
[Illustration: Fig. 19]
2. _Quantitative analysis._ The analysis just described is purely
qualitative and simply shows that water contains hydrogen and oxygen. It
does not prove the absence of other elements; indeed it does not prove
that the hydrogen and oxygen are present in the proportion in which they
are liberated by the electric current. The method may be made
quantitative, however, by weighing the water decomposed and also the
hydrogen and oxygen obtained in its decomposition. If the combined
weights of the hydrogen and oxygen exactly equal the weight of the water
decomposed, then it would be proved that the water consists of hydrogen
and oxygen in the proportion in which they are liberated by the electric
current. This experiment is difficult to carry out, however, so that the
more accurate methods based on synthesis are used.
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