An Elementary Study of ChemistryMcPherson, William
Science
An Elementary Study of Chemistry
McPherson, William
Chemistry
~Uses of water.~ The importance of water in its relation to life and
commerce is too well known to require comment. Its importance to the
chemist has also been pointed out. It remains to call attention to the
fact that it is used as a standard in many physical measurements. Thus
0 deg. and 100 deg. on the centigrade scale are respectively the freezing and
the boiling points of water under normal pressure. The weight of 1 cc.
of water at its point of greatest density is the unit of weight in the
metric system, namely, the gram. It is also taken as the unit for the
determination of the density of liquids and solids as well as for the
measurement of amounts of heat.
HYDROGEN DIOXIDE
~Composition.~ As has been shown, 1 part by weight of hydrogen combines
with 7.94 parts by weight of oxygen to form water. It is possible,
however, to obtain a second compound of hydrogen and oxygen differing
from water in composition in that 1 part by weight of hydrogen is
combined with 2 x 7.94, or 15.88 parts, of oxygen. This compound is
called _hydrogen dioxide_ or _hydrogen peroxide_, the prefixes _di-_ and
_per-_ signifying that it contains more oxygen than hydrogen oxide,
which is the chemical name for water.
~Preparation.~ Hydrogen dioxide cannot be prepared cheaply by the direct
union of hydrogen and oxygen, and indirect methods must therefore be
used. It is commonly prepared by the action of a solution of sulphuric
acid on barium dioxide. The change which takes place may be indicated as
follows:
sulphuric acid + barium dioxide = barium sulphate + hydrogen dioxide
-------------- -------------- --------------- ----------------
hydrogen barium barium hydrogen
sulphur oxygen sulphur oxygen
oxygen oxygen
In other words, the barium and hydrogen in the two compounds exchange
places. By this method a dilute solution of the dioxide in water is
obtained. It is possible to separate the dioxide from the water by
fractional distillation. This is attended with great difficulties,
however, since the pure dioxide is explosive. The distillation is
carried on under diminished pressure so as to lower the boiling points
as much as possible; otherwise the high temperature would decompose the
dioxide.
~Properties.~ Pure hydrogen dioxide is a colorless sirupy liquid having a
density of 1.49. Its most characteristic property is the ease with which
it decomposes into water and oxygen. One part by weight of hydrogen is
capable of holding firmly only 7.94 parts of oxygen. The additional 7.94
parts of oxygen present in hydrogen dioxide are therefore easily
evolved, the compound breaking down into water and oxygen. This
decomposition is attended by the generation of considerable heat. In
dilute solution hydrogen dioxide is fairly stable, although such a
solution should be kept in a dark, cool place, since both heat and light
aid in the decomposition of the dioxide.
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