An Elementary Study of ChemistryMcPherson, William
Science
An Elementary Study of Chemistry
McPherson, William
Chemistry
~Law of definite composition.~ In the earlier days of chemistry there was
much discussion as to whether the composition of a given compound is
always precisely the same or whether it is subject to some variation.
Two Frenchmen, Berthollet and Proust, were the leaders in this
discussion, and a great deal of most useful experimenting was done to
decide the question. Their experiments, as well as all succeeding ones,
have shown that the composition of a pure chemical compound is always
exactly the same. Water obtained by melting pure ice, condensing steam,
burning hydrogen in oxygen, has always 11.18% hydrogen and 88.82% oxygen
in it. Red oxide of mercury, from whatever source it is obtained,
contains 92.6% mercury and 7.4% oxygen. This truth is known as _the law
of definite composition_, and may be stated thus: _The composition of a
chemical compound never varies._
~Law of multiple proportion.~ It has already been noted, however, that
hydrogen and oxygen combine in two different ratios to form water and
hydrogen dioxide respectively. It will be observed that this fact does
not contradict the law of definite composition, for entirely different
substances are formed. These compounds differ from each other in
composition, but the composition of each one is always constant. This
ability of two elements to unite in more than one ratio is very
frequently observed. Carbon and oxygen combine in two different ratios;
nitrogen and oxygen combine to form as many as five distinct compounds,
each with its own precise composition.
In the first decade of the last century John Dalton, an English
school-teacher and philosopher, endeavored to find some rule which holds
between the ratios in which two given substances combine. His studies
brought to light a very simple relation, which the following examples
will make clear. In water the hydrogen and oxygen are combined in the
ratio of 1 part by weight of hydrogen to 7.94 parts by weight of oxygen.
In hydrogen dioxide the 1 part by weight of hydrogen is combined with
15.88 parts by weight of oxygen. The ratio between the amounts of oxygen
which combine with the same amount of hydrogen to form water and
hydrogen dioxide respectively is therefore 7.94: 15.88, or 1: 2.
[Illustration: JOHN DALTON (English) (1766-1844)
Developed the atomic theory; made many studies on the properties and the
composition of gases. His book entitled "A New System of Chemical
Philosophy" had a large influence on the development of chemistry]
Public-domain text, read in full here on John Shaqi.
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