An Elementary Study of ChemistryMcPherson, William
Science
An Elementary Study of Chemistry
McPherson, William
Chemistry
~The properties of electrolytes depend upon the ions present.~ When a
substance capable of dissociating into ions is dissolved in water, the
properties of the solution will depend upon two factors: (1) the ions
formed from the substance; (2) the undissociated molecules. Since the
ions are usually more active chemically than the molecules, most of the
chemical properties of an electrolyte are due to the ions rather than to
the molecules.
The solutions of any two substances which give the same ion will have
certain properties in common. Thus all solutions containing the copper
ion (Cu^{++}) are blue, unless the color is modified by the presence of
ions or molecules having some other color.
EXERCISES
1. Distinguish clearly between the following terms: electrolysis,
electrolyte, electrolytic dissociation, ions, solute, solvent, solution,
saturated solution, and supersaturated solution.
2. Why does the water from some natural springs effervesce?
3. (a) Why does not the water of the ocean freeze? (b) Why will ice
and salt produce a lower temperature than ice alone?
4. Why does shaking or stirring make a solid dissolve more rapidly in a
liquid?
5. By experiment it was found that a certain volume of water was
saturated at 100 deg. with 114 g. of potassium nitrate. On cooling to 0 deg. a
portion of the substance crystallized. (a) How many grams of the
substance remained in solution? (b) What was the strength of the
solution at 18 deg.? (c) How much water had been used in the experiment?
6. (a) 10 g. of common salt were dissolved in water and the solution
evaporated to dryness; what weight of solid was left? (b) 10 g. of
zinc were dissolved in hydrochloric acid and the solution evaporated to
dryness; what weight of solid was left?
7. Account for the fact that sugar sometimes deposits from molasses,
even when no evaporation has taken place.
8. (a) From the standpoint of the theory of electrolytic dissociation,
write the simple equation for a dilute solution of copper sulphate
(CuSO_{4}); this solution is blue. (b) In the same manner, write one
for sodium sulphate; this solution is colorless. (c) How would you
account for the color of the copper sulphate solution?
9. (a) As in the preceding exercise, write a simple equation for a
dilute solution of copper chloride (CuCl_{2}); this solution is blue.
(b) In the same manner, write one for sodium chloride; this solution
is colorless. To what is the blue color due?
10. What component is present in concentrated sulphuric acid that is
almost wanting in very dilute sulphuric acid?
11. Why will vegetables cook faster when boiled in strong salt water
than when boiled in pure water?
12. How do you explain the foaming of soda water?
CHAPTER X
ACIDS, BASES, AND SALTS; NEUTRALIZATION
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