An Elementary Study of ChemistryMcPherson, William
Science
An Elementary Study of Chemistry
McPherson, William
Chemistry
1. _Binary acids._ Acids containing only one element in addition to
hydrogen are called _binary acids_. They are given names consisting of
the prefix _hydro-_, the name of the second element present, and the
termination _-ic_. Examples: hydrochloric acid (HCl); hydrosulphuric
acid (H_{2}S).
2. _Ternary acids._ In addition to the two elements present in binary
acids, the great majority of acids also contain oxygen. They therefore
consist of three elements and are called _ternary acids_. It usually
happens that the same three elements can unite in different proportions
to make several different acids. The most familiar one of these is given
a name ending in the suffix _-ic_, while the one with less oxygen is
given a similar name, but ending in the suffix _-ous_. Examples: nitric
acid (HNO_{3}); nitrous acid (HNO_{2}). In cases where more than two
acids are known, use is made of prefixes in addition to the two suffixes
_-ic_ and _-ous_. Thus the prefix _per-_ signifies an acid still richer
in oxygen; the prefix _hypo-_ signifies one with less oxygen.
~Naming of salts.~ A salt derived from a binary acid is given a name
consisting of the names of the two elements composing it, with the
termination _-ide_. Example: sodium chloride (NaCl). All other binary
compounds are named in the same way.
A salt of a ternary acid is named in accordance with the acid from which
it is derived. A ternary acid with the termination _-ic_ gives a salt
with the name ending in _-ate_, while an acid with termination _-ous_
gives a salt with the name ending in _-ite_. The following table will
make the application of these principles clear:
ACIDS SYMBOL SALTS SYMBOL
Hydrochloric HCl Sodium chloride NaCl
Hypochlorous HClO Sodium hypochlorite NaClO
Chlorous HClO_{2} Sodium chlorite NaClO_{2}
Chloric HClO_{3} Sodium chlorate NaClO_{3}
Perchloric HClO_{4} Sodium perchlorate NaClO_{4}
EXERCISES
1. 25 cc. of a solution containing 40 g. of sodium hydroxide per liter
was found to neutralize 25 cc. of a solution of hydrochloric acid. What
was the strength of the acid solution?
2. After neutralizing a solution of sodium hydroxide with nitric acid,
there remained after evaporation 100 g. of sodium nitrate. How much of
each substance had been used?
3. A solution contains 18 g. of hydrochloric acid per 100 cc. It
required 25 cc. of this solution to neutralize 30 cc. of a solution of
sodium hydroxide. What was the strength of the sodium hydroxide solution
in parts per hundred?
4. When perfectly dry sulphuric acid is treated with perfectly dry
sodium hydroxide, no chemical change takes place. Explain.
5. When cold, concentrated sulphuric acid is added to zinc, no change
takes place. Recall the action of dilute sulphuric acid on the same
metal. How do you account for the difference?
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