An Elementary Study of ChemistryMcPherson, William
Science
An Elementary Study of Chemistry
McPherson, William
Chemistry
6. A solution of hydrochloric acid in benzene does not conduct the
electric current. When this solution is treated with zinc, will hydrogen
be evolved? Explain.
7. (a) Write equation for preparation of hydrogen from zinc and dilute
sulphuric acid. (b) Rewrite the same equation from the standpoint of
the theory of electrolytic dissociation, (c) Subtract the common
SO_{4} ion from both members of the equation, (d) From the resulting
equation, explain in what the preparation of hydrogen consists when
examined from the standpoint of this theory.
8. In the same manner as in the preceding exercise, explain in what the
action of sodium on water to give hydrogen consists.
CHAPTER XI
VALENCE
~Definition of valence.~ A study of the formulas of various binary
compounds shows that the elements differ between themselves in the
number of atoms of other elements which they are able to hold in
combination. This is illustrated in the formulas
HCl, H_{2}O, H_{3}N, H_{4}C.
(hydrochloric acid) (water) (ammonia) (marsh gas)
It will be noticed that while one atom of chlorine combines with one
atom of hydrogen, an atom of oxygen combines with two, an atom of
nitrogen with three, one of carbon with four. The number which expresses
this combining ratio between atoms is a definite property of each
element and is called its _valence_.
DEFINITION: _The valence of an element is that property which determines
the number of the atoms of another element which its atom can hold in
combination._
~Valence a numerical property.~ Valence is therefore merely a numerical
relation and does not convey any information in regard to the intensity
of the affinity between atoms. Judging by the heat liberated in their
union, oxygen has a far stronger affinity for hydrogen than does
nitrogen, but an atom of oxygen can combine with two atoms only of
hydrogen, while an atom of nitrogen can combine with three.
~Measure of valence.~ In expressing the valence of an element we must
select some standard for comparison, just as in the measurement of any
other numerical quantity. It has been found that an atom of hydrogen is
never able to hold in combination more than one atom of any other
element. Hydrogen is therefore taken as the standard, and other elements
are compared with it in determining their valence. A number of other
elements are like hydrogen in being able to combine with at most one
atom of other elements, and such elements are called _univalent_. Among
these are chlorine, iodine, and sodium. Elements such as oxygen,
calcium, and zinc, which can combine with two atoms of hydrogen or other
univalent elements, are said to be _divalent_. Similarly, we have
_trivalent, tetravalent, pentavalent_ elements. None have a valence of
more than 8.
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