An Elementary Study of ChemistryMcPherson, William
Science
An Elementary Study of Chemistry
McPherson, William
Chemistry
~Indirect measure of valence.~ Many elements, especially among the metals,
do not readily form compounds with hydrogen, and their valence is not
easy to determine by direct comparison with the standard element. These
elements, however, combine with other univalent elements, such as
chlorine, and their valence can be determined from the compounds so
formed.
~Variable valence.~ Many elements are able to exert different valences
under differing circumstances. Thus we have the compounds Cu_{2}O and
CuO, CO and CO_{2}, FeCl_{2} and FeCl_{3}. It is not always possible to
assign a fixed valence to an element. Nevertheless each element tends to
exert some normal valence, and the compounds in which it has a valence
different from this are apt to be unstable and easily changed into
compounds in which the valence of the element is normal. The valences of
the various elements will become familiar as the elements are studied in
detail.
~Valence and combining ratios.~ When elements combine to form compounds,
the ratio in which they combine will be determined by their valences. In
those compounds which consist of two elements directly combined, the
union is between such numbers of the two atoms as have equal valences.
Elements of the same valence will therefore combine atom for atom.
Designating the valence of the atoms by Roman numerals placed above
their symbols, we have the formulas
II II II III III IV IV
HCl, ZnO, BN, CSi.
A divalent element, on the other hand, will combine with two atoms of a
univalent element. Thus we have
II II II II
ZnCl_{2} and H_{2}O
(the numerals above each symbol representing the sum of the valences of
the atoms of the element present). A trivalent atom will combine with
three atoms of a univalent element, as in the compound
III III
H_{3}N.
If a trivalent element combines with a divalent element, the union will
be between two atoms of the trivalent element and three of the divalent
element, since these numbers are the smallest which have equal valences.
Thus the oxide of the trivalent metal aluminium has the formula
Al_{2}O_{3}. Finally one atom of a tetravalent element such as carbon
will combine with four atoms of a univalent element, as in the compound
CH_{4}, or with two atoms of a divalent element, as in the compound
CO_{2}.
We have no knowledge as to why elements differ in their combining power,
and there is no way to determine their valences save by experiment.
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