An examination of some methods employed in determining the atomic weight of Cadmium — John Shaqi
An examination of some methods employed in determining the atomic weight of CadmiumBucher, John Emery
History
An examination of some methods employed in determining the atomic weight of Cadmium
Bucher, John Emery
Cadmium; Thesis (Ph. D.)
solution of potassium bromide, first in the cold, then by heating. The
potassium bromide had been made thus: Twice recrystallized potassium
hydrogen tartrate was heated in a platinum dish in a muffle furnace
until it was converted into carbonate, and the excess of carbon burned
off. It was then dissolved in water, filtered and neutralized with some
of the hydrobromic acid already described. The carbonate had been tested
for both sulphuric acid and chlorine with negative results. After the
silver bromide had been digested with the potassium bromide, it was
washed very thoroughly, suspended in water, and a current of hydrogen
sulphide passed into it. This converts it into sulphide hydrobromic acid
being liberated. The acid was drained off on a porcelain plate, and then
distilled a number of times. It was finally tested and found to be
perfectly free from sulphates and also did not contain free bromine.
Having started with an acid which was probably pure and subjected it to
these operations with reagents free from chlorine, there can be no doubt
as to the purity of the resulting acid. The hydrogen sulphide used was
prepared from potassium hydrosulphide as in the sulphide method, and
washed first with a solution of the hydrosulphide, then very thoroughly
with pure water. From the hydrobromic acid obtained, a specimen of
cadmium bromide was prepared as before and sublimed twice in a vacuum.
This specimen was used for determinations IV and V.
Method of Analysis.
The first three determinations were made exactly like those in the
chloride method. The last two were also made in the same manner, only
the washing of the precipitate was varied. After the silver bromide had
been contracted by warming on a water-bath it was washed by decantation
and then agitated violently with cold water to remove occluded nitrates,
but it was then so finely divided that it could not be filtered. The
artifice used by Stas to contract it a second time was to pass a current
of steam into the milky liquid. This was tried here, but for some reason
or other did not work very well, and considerable difficulty was had in
filtering it. The results of the five determinations are tabulated
below. All weighings are reduced to the vacuum standard on the basis of
Sp. Gr. of CdBr_{2} = 4.6 and Sp. Gr. AgBr = 6.62.
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