An Introduction to Chemical ScienceWilliams, Rufus P. (Rufus Phillips)
Science
An Introduction to Chemical Science
Williams, Rufus P. (Rufus Phillips)
Chemistry
Write the common formulae for the first ten of this series. This
is the olefiant-gas series, and to it belong oxalic and tartaric
acids, glycerin, and a vast number of other compounds, many of
which are derived by replacements.
303. Other Series.--In addition to the two series of hydro-
carbons above given, CnH2n+2 and CnH2n, other series are known
with the general formulm CnH2n-2, CnH2n-4, CnH2n-6, CnH2n-8,
etc., as far as CnH2n-32, or C26H2O. Each of these has a large
number of representatives, as was found in the marsh-gas series.
Not far from two hundred direct compounds of C and H are known,
not to mention substitutions. The formula CnH2n-6 represents a
large and interesting group of compounds, called the benzine
series. This is the basis of the aniline dyes, and of many
perfumes and flavors.
Chapter LV.
ILLUMINATING GAS.
304. Source.--The three main elements in combustion are O, H, C.
Air supplies O, the supporter; C and H are usually united, as
hydro-carbons, in luminants and combustibles. H gives little
light in burning; C gives much. The fibers of plants contain
hydro-carbons, and by destructive distillation these are
separated, as gases, from wood and coal, and used for
illuminating purposes. Mineral coal is fossilized vegetable
matter; anthracite has had most of the volatile hydro-carbons
removed by distillation in the earth; bituminous and cannel coals
retain them. These latter coals are distilled, and furnish us
illuminating gas.
Experiment 129.--Put into a t.t. 20 g. of cannel coal in fine
pieces. Heat, and collect the gas over H2O. Test its
combustibility. Notice any impurities, such as tar, adhering to
the sides of the t.t., or of the receiver after combustion. Try
to ignite a piece of cannel coal by holding it in a Bunsen flame.
Is it the C which burns, or the hydrocarbons? Distil some wood
shavings in a small ignition-tube, and light the escaping gas.
305. Preparation and Purification.--To make illuminating gas,
fire-clay retorts filled with coal are heated to 1100 degrees or
more, over a fire of coke or coal. Tubes lead the distilled gas
into a horizontal pipe, called the hydraulic main, partly filled
with water, into which the ends of the gas-pipe dip. The gas then
passes through condensers consisting of several hundred feet of
vertical pipe, through high towers, called washers, in which a
fine spray Fig. 60. Gas Works.
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