An Introduction to Chemical ScienceWilliams, Rufus P. (Rufus Phillips)
Science
An Introduction to Chemical Science
Williams, Rufus P. (Rufus Phillips)
Chemistry
A, furnace; C, retorts containing coal; T, gas-tubes leading to
B, the hydraulic main; D, condensers; O, washers, with a spray of
water, and sometimes coke; M, purifiers-ferric oxide or lime; G,
gas-holder. In C remain the coke and gas carbon. At B, D, E, and
O, coal tar, H2O, NH3, CO2, and SO2 are removed. At M are taken
out H2S and CO2.of water falls, into chambers with shelves
containing the purifiers CaO or hydrated Fe2O3, and finally into
a gas-holder, whence it is distributed. At the hydraulic main,
condensers, washers, and purifiers, certain impurities are
removed froth the gas. Coke is the solid C residue after
distillation. Gas-carbon, also a solid, is formed by the
separation of the heavier hydro-carbons at high temperature, and
is deposited on the sides of the retort.
Coal gas, as it leaves the retort, has many impurities. It is
accompanied with about 3 its weight of coal tar, 1/2 its weight
of H2O vapor, 1/50 NH3, 1/20 CO2, 1/20 to 1/50 H2S, 1/300 to
1/600 S in other forms. The tar is mostly taken out at the
hydraulic main, which also withdraws some H2O with other
impurities in solution. The condensers remove the rest of the
tar, and the H2O, except what is necessary to saturate the gas.
At the main, the condensers, and the washers, NH3 is abstracted,
CO2 and H2S are much reduced, and the other S compounds are
diminished. Lime purification removes CO2 and H2S, and, to some
extent, other S compounds. Iron purification removes H2S. Fe2O3 +
3 H2S = 2 FeS + S + 3 H2O.
The FeS is revivified by exposure to the air. 2 FeS + O3 = Fe2O3
+ 2S. It can then be used again. H2S, if not separated, burns
with the gas, forming H2S03, which oxidizes in the air to H2SO4;
hence the need of removing it. CO2 diminishes the illuminating
power.
306. Composition.--Even when freed from its impurities coal-gas
is a very complex mixture, the chief components being nearly as
follows:--
Percent Diluents, having little C, give
H 45) very little light. Notice the small
CH, 41) diluents. percentage of luminants, or light-
CO 5 ) giving compounds, also the proportion
C,HB 1.3) of C to H in them.
C,H6 1.2)luminants.
CZH4 2.5) Cannel coal contains more of
C02 2) impurities. the heavy bydro-carbons, CnH2n,
N, etc. 2) etc., than the ordinary bituminous
100 coal. Ten per cent of the coal should be
cannel; naphtha is, however, often employed to subserve the same
purpose, one ton of ordinary bituminous coal requiring four gallons
of oil.
In Boston, 7,000,000 cubic feet of gas have been burned in one
day, consuming 500 tons of coal; the average is not more than
half that quantity. Of the other products, coke is employed for
heating purposes, gas carbon is used to some extent in electrical
work, and coal-tar is the source of very many artificial products
that were formerly only of natural origin. NH3, is the main
source of ammonium salts, and S is made into H2SO4.
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