An Introduction to Chemical ScienceWilliams, Rufus P. (Rufus Phillips)
Science
An Introduction to Chemical Science
Williams, Rufus P. (Rufus Phillips)
Chemistry
319. Carbon and Water.--Some very important organic compounds
have H and O, in the proper proportion to form water, united with
C. The three leading ones are sugar, C12H22O11 or C12(H2O)11,
starch, C6H10O6, or ?, and cellulose, C18H30O15 or ?. Note the
significance of the name carbo-hydrates as applied to them.
320. Sugars may be divided into two classes,--the sucroses,
C12H22O11, and the glucoses, C6H12O6. Sucrose, the principal
member of the first class, is obtained from the juice of the
maple, the palm, the beet and the sugarcane; in Europe largely
from the beet, in America from cane. Granulated sugar is that
which has been refined; brown sugar is the unrefined. From the
sap evaporated by boiling, brown sugar crystallizes, leaving
molasses, which contains glucose and other substances. Good
molasses has but a small percentage of glucose. To refine brown
sugar it is dissolved in water, a small quantity of blood is
added to remove certain vegetable substances, after which it is
filtered through animal charcoal, i.e. bone-black, a process
which takes out the coloring-matter. The water is then evaporated
in vacuum-pans, so as to boil at about 74 degrees and to prevent
conversion into grape sugar. By this process much glucose or
syrup is formed, which is separated from the crystalline sucrose
by rapidly revolving centrifugal machines. Great quantities of
sucrose are used for food by all civilized nations. A single
refinery in New York purifies 2,000,000 pounds per day.
321. Glucose, or invert sugar, the principal member of the second
class, consists of two distinct kinds of sugar, --dextrose and
levulose. These differ in certain properties, but have the same
symbol. Both are found in equal parts in ripe fruits, while
sucrose occurs in the unripe. Honey contains these three kinds of
sugar.
Sucrose, by the action of heat, weak acids, or ferments, may be
resolved into the other two varieties. C12H22O11 + H2O = C6H12O6
+ C6H12O6. No mode of reversing this process, or of transforming
glucose into sucrose is known. Glucose is easily made from starch
or from the cellulose in cotton rags, sawdust, etc. If boiled
with dilute H2SO4 starch takes up water and becomes glucose.
C6H10O5 + H2O = C6H12O6.
CaCO3 is added to precipitate the H2SO4, which remains unchanged.
State the reaction. The product is filtered and the filtrate is
evaporated. Much glucose is made from the starch of corn and
potatoes.
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