An Introduction to Chemical ScienceWilliams, Rufus P. (Rufus Phillips)
Science
An Introduction to Chemical Science
Williams, Rufus P. (Rufus Phillips)
Chemistry
322. Starch is found in all plants, especially in grains, seeds,
and tubers. Green plants--those containing chlorophyll--
manufacture their own starch from CO2 and H2O. These chlorophyll
grains are the plant's chemical laboratories, and hundreds of
thousands of them exist in every leaf. CO2 and a very little H2O
enter the leaf from the air, H2O being also drawn up through the
root and stem from the earth. In some unknown way in the leaf,
light has the power of synthesizing these into starch and setting
free O, which is returned to the atmosphere.6 CO2 + 5 H2O =
C6H10O5 + 12 O. As no such change takes place in darkness, all
green plants must have light. Parasitic plants, which are usually
colorless, obtain starch ready-made from those on which they
feed.
323. Uses.--Glucose is used in the manufacture of alcohol and
cheap confectionery, and in adulterating sucrose. It is only two-
thirds as sweet as the latter. The seeds of all plants contain
starch for the germinating sprout to feed upon; but starch is
insoluble, and hence useless until it is converted into glucose.
This is effected by the action of warmth, moisture, and a ferment
in the seed. Glucose is soluble and is at first the plant's main
food.
Commercial starch is made in the United States chiefly from corn;
in Europe, from potatoes. Differences in the size of starch
granules enable microscopists to determine the plant to which
they belong.
324. Cellulose, or woody fiber, is the basis of all vegetable
cell walls. Cotton fiber represents almost pure cellulose. From
it are made paper and woven tissues. In paper manufacture, woody
fiber is made into a pulp, washed, bleached, filtered, hot-
pressed, and sometimes glazed. Parchment paper, vegetable
parchment, is made by dipping unglazed paper for half a minute
into cold dilute H2SO4, 1 part H2O, 2 1/2 parts H2SO4, and then
washing. The fiber, by chemical change, is thus toughened. The
cell walls of wood are impure cellulose; hence the inferior
quality of paper made from wood-pulp. Paper is now employed for a
large number of purposes for which wood has heretofore been used,
such as for barrels, pails, and other hollow ware, wheels,
etc.
325. Gun-cotton is made by treating cotton fiber with H2SO4
and HNO3, washing and drying. To all appearances no change has
taken place, but the substance has become an explosive compound.
326. Dextrin, a gummy substance used for the backs of postage
stamps, is a carbo-hydrate, as in fact are gums in general.
Dextrin is made by heating starch with H2SO4 at a lower
temperature than for dextrose.
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