An Introduction to Chemical ScienceWilliams, Rufus P. (Rufus Phillips)
Science
An Introduction to Chemical Science
Williams, Rufus P. (Rufus Phillips)
Chemistry
327. Zylonite and Celluloid. -These two similar substances embody
the latest use of cellulose in manufactured articles. For
zylonite, linen paper is cut into strips two feet by one inch,
soaked ten minutes in a mixture of H2SO4 and HNO3, a process
called nitration, washed for several hours, then ground to a fine
pulp, and thoroughly dried. It is then similar to pyroxiline.
Aniline coloring-matter of any desired shade is added, after
which it is dissolved by soaking some hours in alcohol and
camphor, the liquid is evaporated, and the substance is kneaded
between steam-heated iron rollers, dried with hot air, and
finally subjected to great pressure, to harden it, and cut into
sheets. Zylonite is combustible at a low temperature, and when in
the pyroxiline stage, explosively so. Ivory, coral, amber, bone,
tortoise shell, malachite, etc., are so closely imitated that the
imitation can only be detected by analysis. Collars, combs,
canes, piano-keys, and jewelry, are manufactured from it, and it
can be made transparent enough for windows.
CHAPTER LIX
CHEMISTRY OF FERMENTATION.
328. Ferments.--A large number of chemical changes are brought
about through the direct agency of bodies called ferments; their
action is called fermentation. Ferments are sometimes lifeless
chemical products found in living bodies; but in other cases they
are humble plants.
329. Yeast is one of the most common of living ferments, wild
yeast being a microscopic plant found on the ground near apple-
trees and grape-vines, and often in the air. The cultivated
variety is sold by grocers. The temperature best suited to the
rapid multiplication of the germs forming the ferment plant is 25
degrees to 35 degrees.
330. Alcoholic and Acetic Fermentation.--The changes which the
juice of the apple undergoes in forming cider and vinegar are a
good illustration of fermentation by a living plant. Apple-juice
contains sucrose. Yeast germs from the air, getting into this
unfermented liquor, cause it to "work." This process changes
sucrose to glucose, and glucose to alcohol and CO2, and is known
as alcoholic fermentation. The latter reaction, C6H12O6 = 2 C2H6O
+ 2 CO, is only partially correct, as other products are formed.
The juice has now become cider; the sugar alcohol. After a time,
if left exposed, another organism finds its way to the alcohol,
and transforms it into acetic acid, HC2H8O2, and H2O. This
process is called acetic fermentation. C2H6O + O2 = HC2H3O2 +
H2O. For this fermentation, a liquor should not have over ten per
cent of alcohol. Mother of vinegar consists of the germs that
caused the fermentation. Still a third species of ferment may
cause another action, changing acetic acid to H2O and CO2. The
vinegar then tastes flat. HC2H3O2 + 4 O = 2H2O + 2 CO2.
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